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5,5',5''-(benzene-1,3,5-triyltris(ethyne-2,1-diyl))tris(3-(tert-butyl)-2-hydroxybenzaldehyde)

5,5',5''-(benzene-1,3,5-triyltris(ethyne-2,1-diyl))tris(3-(tert-butyl)-2-hydroxybenzaldehyde)

CAS NO.:705930-83-2分子式:C45H42O6分子量:678.81138
产品名称:3,​3',​3''-​(1,​3,​5-​Benzenetriyltri-​2,​1-​ethynediyl)​tris[5-​(1,​1-​dimethylethyl)​-​6-​hydroxybenzaldehyde]
其他名称:
CAS:705930-83-2
结构信息
分子式 C45H42O6 分子量 678.81138
性状照片  
性质说明
1) 可溶于DCM、DMF、DMSO等
2) 2-8℃密封保存
合成应用
1) 可作为单体用于合成COF材料:salenCOF [r3]
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Nielsen, Morten; Thomsen, Anne H.; Jensen, Torben R.; Jakobsen, Hans J.; Skibsted, Jorgen; Gothelf, Kurt V.; Eur. J. Org. Chem. 2005, (2), 342-347, DOI: 10.1002/ejoc.200400451 ; Formation and structure of conjugated salen-​cross-​linked polymers and their application in asymmetric heterogeneous catalysis
2) Weigelt, Sigrid; Bombis, Christian; Busse, Carsten; Knudsen, Martin M.; Gothelf, Kurt V.; Laegsgaard, Erik; Besenbacher, Flemming; Linderoth, Trolle R.; ACS Nano 2008, 2(4), 651-660, DOI: 10.1021/nn7004365 ; Molecular Self-​Assembly from Building Blocks Synthesized on a Surface in Ultrahigh Vacuum: Kinetic Control and Topo-​Chemical Reactions
3) Li, Li-Hua; Feng, Xiao-Lin; Cui, Xiao-Hui; Ma, Yun-Xiang; Ding, San-Yuan; Wang, Wei.; J. Am. Chem. Soc. 2017, 139(17), 6042-6045, DOI: 10.1021/jacs.7b01523 ; Salen-​Based Covalent Organic Framework
4) Kannan, Masanam; De, Pinaki Bhusan; Pradhan, Sourav; Punniyamurthy, Tharmalingam; ChemistrySelect 2018, 3(3), 859-863, DOI: 10.1002/slct.201702607 ; Chiral Fe-​Dendrimer-​Catalyzed Domino Michael and Aldol Reactions of Chalcones with 1,​4-​Dithiane-​2,​5-​diol

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