产品名称：N,N′,N′′-bis-(4-carboxylate)trimesicamide其他名称：H3bcta ; H3btcit; H3BTCB;4,4',4''-[1,3,5-Benzenetriyltris(carbonylimino)]trisbenzoic acid CAS：120360-51-2
结构信息
| 分子式 |
C30H21N3O9 |
分子量 |
567.50244 |
| 性状照片 |
 |
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:DUT-32 [r4]; Y-PCP, La-PCP [r4]; tp-PMBB-1-asc-3 [r5]; 3D-ROD-1 [r6]
表征图谱
参考文献
1) Aharoni, S. M.; Edwards, S. F.; Macromolecules (1989), 22(8), 3361-3374, DOI: 10.1021/ma00198a030 ; Gels of rigid polyamide networks
2) Bernet, Andreas; Albuquerque, Rodrigo Q.; Behr, Marina; Hoffmann, Sebastian T.; Schmidt, Hans-Werner; Soft Matter 2012, 8(1), 66-69, DOI: 10.1039/C1SM06789C ; Formation of a supramolecular chromophore: a spectroscopic and theoretical study
3) Duan, Jingui; Higuchi, Masakazu; Foo, Maw Lin; Horike, Satoshi; Rao, Koya Prabhakara; Kitagawa, Susumu; Inorg. Chem. 2013, 52(14), 8244-8249, DOI: 10.1021/ic401157n ; A Family of Rare Earth Porous Coordination Polymers with Different Flexibility for CO2/C2H4 and CO2/C2H6 Separation
4) Gruenker, Ronny; Bon, Volodymyr; Mueller, Philipp; Stoeck, Ulrich; Krause, Simon; Mueller, Uwe; Senkovska, Irena; Kaskel, Stefan; Chem. Commun., 2014,50, 3450-3452, DOI: 10.1039/C4CC00113C ; A new metal–organic framework with ultra-high surface area
5) Schoedel, Alexander; Cairns, Amy J.; Belmabkhout, Youssef; Wojtas, Lukasz; Mohamed, Mona; Zhang, Zhenjie; Proserpio, Davide M.; Eddaoudi, Mohamed; Zaworotko, Michael J.; Angew. Chem., Int. Ed. 2013, 52(10), 2902-2905, DOI: 10.1002/anie.201206042 ; The asc Trinodal Platform: Two-Step Assembly of Triangular, Tetrahedral, and Trigonal-Prismatic Molecular Building Blocks6) Zhang, Yu-Feng; Zhang, Zong-Hui; Ritter, Logan; Fang, Han; Wang, Qian; Space, Brian; Zhang, Yue-Biao; Xue, Dong-Xu; Bai, Junfeng; Journal of the American Chemical Society 2021, 143(31), 12202-12211, DOI: 10.1021/jacs.1c04946 ; New Reticular Chemistry of the Rod Secondary Building Unit: Synthesis, Structure, and Natural Gas Storage of a Series of Three-Way Rod Amide-Functionalized Metal-Organic Frameworks
