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4-(4H-1,2,4-三氮唑-4-基)-4H-1,2,4-三氮唑

4,4'-Bi-4H-1,2,4-triazole

CAS NO.:16227-15-9分子式:C4H4N6分子量:136.11476
产品名称: 4,​4'-​azo-​1,​2,​4-​triazole
其他名称: 4-(4H-1,2,4-三氮唑-4-基)-4H-1,2,4-三氮唑;atrz; BTR;4,​4'-​bis(1,​2,​4-​triazole)​
CAS: 16227-15-9
结构信息
分子式  C4H4N6 分子量  136.11476
性状照片
性质说明
1) 16227-15-9 溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:Ag(btr) [r3, r4]
表征图谱
HNMR
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Du, Y.; Su, H.; Fei, T.; Hu, B.; Zhang, J.; Li, S.; Pang, S.; Nie, F.; Cryst. Growth. Des. 2018, 18(10), 5896-5903, DOI: 10.1021/acs.cgd.8b00640 ; Structure–Property Relationship in Energetic Cationic Metal–Organic Frameworks: New Insight for Design of Advanced Energetic Materials 
2) Gao, Q.; Xu, J.; Cao, D.; Chang, Z.; Bu, X.; Angew. Chem., Int. Ed. 2016, 55(48), 15027-15030, DOI:10.1002/anie.201608250 ; A Rigid Nested Metal–Organic Framework Featuring a Thermoresponsive Gating Effect Dominated by Counterions
3) Li, X.; Gong, Y.; Zhao, H.; Wang, R.; Inorg. Chem. 2014, 53(22), 12127-12134, DOI:10.1021/ic501978u ; Anion-Directed Assemblies of Cationic Metal–Organic Frameworks Based on 4,4′-Bis(1,2,4-triazole): Syntheses, Structures, Luminescent and Anion Exchange Properties 
4) Li, X.; Xu, H.; Kong, F.; Wang, R.; Angew. Chem., Int. Ed. 2013, 52(51), 13769-13773, DOI:10.1002/anie.201307650 ; A Cationic Metal–Organic Framework Consisting of Nanoscale Cages: Capture, Separation, and Luminescent Probing of Cr2O72− through a Single‐Crystal to Single‐Crystal Process
5) Huang, Y.; Zhao, X.; Shi, W.; Liu, W.; Chen, Z.; Cheng, P.; Liao, D.; Yan, S.; DOI:10.1021/cg8002564 ; Anions-Directed Metal-Mediated Assemblies of Coordination Polymers Based on the Bis(4,4′-bis-1,2,4-triazole) Ligand
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