产品名称:1H,7H-[1,4]Dioxino[2,3-f:5,6-f']bisbenzotriazole
其他名称:H2btdd
CAS:1276042-43-3
其他名称:H2btdd
CAS:1276042-43-3
结构信息
分子式 | C12H6N6O2 | 分子量 | 266.21504 | ||
性状照片 |
性质说明
1) 1276042-43-3 溶于DMF、DMSO等
2) 室温密封保存
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料,如:MFU-4l [r1]; MCl2(BTDD) (M=Mn, Co, Ni) [r2]; Ni-CFA-1 [r4]; MIT-20d [r3]
表征图谱
参考文献
1) Denysenko, D.; Grzywa, M.; Tonigold, M.; Streppel, B.; Krkljus, I.; Hirscher, M.; Mugnaioli, E.; Kolb, U.; Hanss, J.; Volkmer, D. Chem.-Euro. J. 2011, 17(6), 1837-1848 DOI: 10.1002/chem.201001872 ; Elucidating Gating Effects for Hydrogen Sorption in MFU‐4‐Type Triazolate‐Based Metal–Organic Frameworks Featuring Different Pore Sizes
2) Rieth, A.; Tulchinsky, Y.; Dinca, M. J. Am. Chem. Soc., 2016, 138(30), 9401-9404, DOI: 10.1021/jacs.6b05723 ; High and Reversible Ammonia Uptake in Mesoporous Azolate Metal–Organic Frameworks with Open Mn, Co, and Ni Sites
3) Park, S.; Tulchinsky, Y.; Dinca, M. J. Am. Chem. Soc., 2017, 139(38), 13260-13263 DOI: 10.1021/jacs.7b06197 ; Single-Ion Li+, Na+, and Mg2+ Solid Electrolytes Supported by a Mesoporous Anionic Cu–Azolate Metal–Organic Framework
4) Metzger, E.; Comito, R.; Wu, Z.; Zhang, G.; Dubey, R.; Xu, W.; Miller, J.; Dinca, M.; DOI: 10.1021/acssuschemeng.8b05703 ; Highly Selective Heterogeneous Ethylene Dimerization with a Scalable and Chemically Robust MOF Catalyst