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5,5-二乙烯基-2,2-联吡啶

5,5-Divinyl-2,2-bipyridine

CAS NO.:932396-96-8分子式:C14H12N2分子量:208.25848
产品名称: 5,5'-divinyl-2,2'-bipyridine
其他名称: 5,​5-​dvbpy
CAS: 932396-96-8
结构信息
分子式  C14H12N2 分子量  208.26
性状照片  
性质说明
1) 溶于氯仿、DMF、DMSO等
2) 2-8℃ 密封保存
合成应用
1) 可作为单体用于合成COF材料: [Ru(5,​5'-​dvbpy)​(bpy)​2]​ [r3]; [Ru(dvb)2((PO3H2)2bpy)]2+ [r4]
表征图谱
HNMR
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Cheng, Yixiang; Zou, Xiaowei; Zhu, Dan; Zhu, Tingshun; Liu, Yan; Zhang, Shuwei; Huang, Hui; J. Polymer Sci. 2007, 45(4), 650-660, DOI: 10.1002/pola.21766 ; Synthesis and characterization of chiral polymer complexes incorporating polybinaphthyls, bipyridine, and Eu(III)
2) Liu, Yan; Zhang, Shuwei; Miao, Qian; Zheng, Lifei; Zong, Lili; Cheng, Yixiang; Macromolecules 2007, 40(14), 4839-4847, DOI: 10.1021/ma0701437 ; Fluorescent Chemosensory Conjugated Polymers Based on Optically Active Polybinaphthyls and 2,​2'-​Bipyridyl Units
3) Nie, Hai-Jing; Shao, Jiang-Yang; Wu, Jing; Yao, Jiannian; Zhong, Yu-Wu; Organometallics 2012, 31(19), 6952-6959, DOI: 10.1021/om300730f ; Synthesis and Reductive Electropolymerization of Metal Complexes with 5,​5'-​Divinyl-​2,​2'-​Bipyridine
4) Ashford, Dennis L.; Lapides, Alexander M.; Vannucci, Aaron K.; Hanson, Kenneth; Torelli, Daniel A.; Harrison, Daniel P.; Templeton, Joseph L.; Meyer, Thomas J.; J. Am. Chem. Soc. 2014, 136(18), 6578-6581, DOI: 10.1021/ja502464s ; Water Oxidation by an Electropolymerized Catalyst on Derivatized Mesoporous Metal Oxide Electrodes
5) Dai, Zhifeng; Sun, Qi; Liu, Xiaolong; Guo, Liping; Li, Jixue; Pan, Shuxiang; Bian, Chaoqun; Wang, Liang; Hu, Xin; Meng, Xiangju; Zhao, Leihong; Deng, Feng; Xiao, Feng-Shou; ChemSusChem 2017, 10(6), 1186-1192, DOI: 10.1002/cssc.201601375 ; A Hierarchical Bipyridine-​Constructed Framework for Highly Efficient Carbon Dioxide Capture and Catalytic Conversion
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