产品名称:2,2′-bis(trifluoromethyl)-4,4′-biphenyldicarboxylic acid
其他名称:H2BPDC-m-2CF3;
CAS:89803-71-4
3) Chen, Cheng-Xia; Qiu, Qian-Feng; Pan, Mei; Cao, Chen-Chen; Zhu, Neng-Xiu; Wang, Hai-Ping; Jiang, Ji-Jun; Wei, Zhang-Wen; Su, Cheng-Yong; Chem. Commun. 2018, 54(97), 13666-13669, DOI: 10.1039/c8cc07441k ; Tunability of fluorescent metal-organic frameworks through dynamic spacer installation with multivariate fluorophores
其他名称:H2BPDC-m-2CF3;
CAS:89803-71-4
结构信息
分子式 | C16H8O4F6 | 分子量 | 378.22272 | ||
性状照片 |
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:UiO-67-m-2CF3 [r1]; LIFM-28 [r3]; LIFM-100 [r4, r5];PCN-700 [r6]
表征图谱
参考文献
1) Wang, Keke; Huang, Hongliang; Zhou, Xiaocong; Wang, Qin; Li, Guijie; Shen, Haimin; She, Yuanbin; Zhong, Chongli; Inorg. Chem. 2019, 58(9), 5725-5732, DOI: 10.1021/acs.inorgchem.9b00088 ; Highly Chemically Stable MOFs with Trifluoromethyl Groups: Effect of Position of Trifluoromethyl Groups on Chemical Stability
2) gers, H. G.; Gaudiana, Russell A.; Hollinsed, W. C.; Kalyanaraman, P. S.; Manello, J. S.; McGowan, C.; Minns, R. A.; Sahatjian, R.; Macromolecules 1985, 18(6), 1058-1068, DOI: 10.1021/ma00148a003 ; Highly amorphous, birefringent, para-linked aromatic polyamides4) Qiu, Qian-feng; Chen, Cheng-Xia; Wei, Zhang-Wen; Cao, Chen-Chen; Zhu, Neng-Xiu; Wang, Hai-Ping; Wang, Dawei; Jiang, Ji-Jun; Su, Cheng-Yong; Inorg. Chem. 2019, 58(1), 61-64, DOI: 10.1021/acs.inorgchem.8b02993 ; A Flexible Cu-MOF as Crystalline Sponge for Guests Determination
5) Qiu, Qian-Feng; Chen, Cheng-Xia; Zeng, Zheng; Wei, Zhang-Wen; Zhu, Neng-Xiu; Cao, Chen-Chen; Wang, Wei; Wang, Dawei; Wang, Hai-Ping; Jiang, Ji-Jun; Inorg. Chem. 2020, 59(20), 14856-14860, DOI: 10.1021/acs.inorgchem.0c02123 ; A Flexible-Robust Copper(II) Metal-Organic Framework Constructed from a Fluorinated Ligand for CO2/R22 Capture
6) Fan Yang, Jiajia Wang, You Wang, Benling Yu, Yiwen Cao, Jiawei Li, Linlin Wu, Jianhan Huang, You-Nian Liu; Angew. Chem. Int. Ed. DOI: 10.1002/anie.202318115, Perfluoroalkyl-Decorated Noble-Metal-Free MOFs for the Highly Efficient One-Pot Four-Component Coupling between Aldehydes, Amines, Alkynes, and Flue Gas CO2
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