CAS 868046-56-4|H4TCHB|H4TTTA|CHEMSOON

产品名称：3,3',5,5'-tetrakis(4-carboxyphenyl)-2,2',4,4',6,6'-hexamethyl-1,1'-biphenyl
其他名称：H4TCHB; H4TTTA;
CAS：868046-56-4

结构信息

分子式	C46H38O8		分子量	718.78912
性状照片

性质说明

1) 可溶于DMF、DMSO等
2) 室温密封保存

合成应用

1) 可作为配体用于合成MOF材料：MFM-133(M) (M = Zr, Hf) [r2]

表征图谱

HNMR

FTIR

HPLC

参考文献

1) Moorthy, J.; Natarajan, R.; Venugopalan, P.; J. Org. Chem. 2005, 70(21), 8568-8571, DOI: 10.1021/jo051205z ; Three-Dimensional Four-Connecting Organic Scaffolds with a Twist: Synthesis and Self-Assembly

2) Yan, Y.; O'Connor, A.; Kanthasamy, G.; Atkinson, G.; Allan, D.; Blake, A.; Schroder, M.; J. Am. Chem. Soc. 2018, 140(11), 3952-3958, DOI: 10.1021/jacs.7b11747 ; Unusual and Tunable Negative Linear Compressibility in the Metal–Organic Framework MFM-133(M) (M = Zr, Hf)

3) Lv, X.; Yuan, S.; Xie, L.; Darke, H.; Chen, Y.; He, T.; Dong, C.; Wang, B.; Zhang, Y.; Li, J.; Zhou, H.; J. Am. Chem. Soc. 2019, 141(26), 10283-10293, DOI:10.1021/jacs.9b02947 ; Ligand Rigidification for Enhancing the Stability of Metal–Organic Frameworks

868046-56-4-CS017591.pdf

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3,3',5,5'-四(4-羧苯基)-2,2',4,4',6,6'-六甲基-1,1'-联苯

3,3',5,5'-tetrakis(4-carboxyphenyl)-2,2',4,4',6,6'-hexamethyl-1,1'-biphenyl

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3,3',5,5'-四(4-羧苯基)-2,2',4,4',6,6'-六甲基-1,1'-联苯

3,​3',​5,​5'-​tetrakis(4-​carboxyphenyl)​-​2,​2',​4,​4',​6,​6'-​hexamethyl-​1,​1'-​biphenyl

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3,3',5,5'-tetrakis(4-carboxyphenyl)-2,2',4,4',6,6'-hexamethyl-1,1'-biphenyl