产品名称：Tetrakis(trimethylsilylethynylphenyl)ethylene
其他名称：TPE-(TMS)4;Silane, [1,2-ethenediylidenetetrakis(4,1-phenylene-2,1-ethynediyl)]tetrakis[trimethyl- (9CI); 1,1',1'',1'''-(1,2-Ethenediylidene)tetrakis[4-[2-(trimethylsilyl)ethynyl]benzene]; 1,1,2,2-Tetrakis(4-((trimethylsilyl)ethynyl)phenyl)ethene;
CAS：741259-14-3
3) Yuan, Kai; Guo-Wang, Peiyao; Hu, Ting; Shi, Lei; Zeng, Rong; Forster, Michael; Pichler, Thomas; Chen, Yiwang; Scherf, Ullrich; Chem. Mater. 2015, 27, 21, 7403-7411, DOI: 10.1021/acs.chemmater.5b03290 ; Nanofibrous and Graphene-Templated Conjugated Microporous Polymer Materials for Flexible Chemosensors and Supercapacitors
其他名称：TPE-(TMS)4;Silane, [1,2-ethenediylidenetetrakis(4,1-phenylene-2,1-ethynediyl)]tetrakis[trimethyl- (9CI); 1,1',1'',1'''-(1,2-Ethenediylidene)tetrakis[4-[2-(trimethylsilyl)ethynyl]benzene]; 1,1,2,2-Tetrakis(4-((trimethylsilyl)ethynyl)phenyl)ethene;
CAS：741259-14-3
结构信息
| 分子式 | C46H52Si4 | 分子量 | 717.24708 | ||
| 性状照片 | |||||
性质说明
1) 可溶于DCM、DMF、DMSO等
2) 2-8℃密封保存
2) 2-8℃密封保存
合成应用
1) 可作为单体用于合成COF材料：Conjugated microporous polymers (CMPs) PTEPE-TBPE
表征图谱
参考文献
1) Sengupta, Saumitra; Synlett 2004, (7), 1191-1194, DOI: 10.1055/s-2004-822929 ; Synthesis of highly conjugated two-dimensional molecular scaffolds via Pd-catalyzed reactions on a tetraphenylethylene core
2) Wang, Jian; Mei, Ju; Zhao, Engui; Song, Zhegang; Qin, Anjun; Sun, Jing Zhi; Tang, Ben Zhong; Macromolecules 2012, 45(19), 7692-770, DOI: 10.1021/ma3017037 ; Ethynyl-Capped Hyperbranched Conjugated Polytriazole: Click Polymerization, Clickable Modification, and Aggregation-Enhanced Emission4) Ramachandran, Elumalai; Dhamodharan, Raghavachari; J. Mater. Chem. C 2017, 5(40), 10469-10476, DOI: 10.1039/C7TC03211K ; Tetrakis(trialkylsilylethynylphenyl)ethenes: mechanofluorochromism arising from steric considerations with an unusual crystal structure
5) Wang, Zheng; Zhu, Cheng-Yi; Mo, Jun-Ting; Fu, Peng-Yan; Zhao, Yan-Wu; Yin, Shao-Yun; Jiang, Ji-Jun; Pan, Mei; Su, Cheng-Yong; Angew. Chem., Int. Ed. 2019, 58(29), 9752-9757, DOI: 10.1002/anie.201905186 ; White-Light Emission from Dual-Way Photon Energy Conversion in a Dye-Encapsulated Metal-Organic Framework
