产品名称: 1,4-bis(4-pyridyl)-2,3-diaza-1,3-butadiene)
其他名称:4-bpdb; bpdab; bphz; azpy;1,2-bis(4-pyridylmethylene)hydrazine; N,N'-bis-pyridin-4-ylmethylenehydrazine
CAS:6957-22-8
其他名称:4-bpdb; bpdab; bphz; azpy;1,2-bis(4-pyridylmethylene)hydrazine; N,N'-bis-pyridin-4-ylmethylenehydrazine
CAS:6957-22-8
结构信息
分子式 | C12H10N4 | 分子量 | 210.2346 | ||
性状照片 |
性质说明
1) 6957-22-8 可溶于DCM、DMF、DMSO等
2) 室温密封保存
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:TMU-4 [r2]
表征图谱
参考文献
1) Singh, Divyendu; Nagaraja, C. M.; Cryst. Growth Des. 2015, 15(7), 3356-3365, DOI: 10.1021/acs.cgd.5b00450 ; Auxiliary Ligand-Assisted Structural Variation of Cd(II) Metal–Organic Frameworks Showing 2D → 3D Polycatenation and Interpenetration: Synthesis, Structure, Luminescence Properties, and Selective Sensing of Trinitrophenol
2) Tahmasebi, E.; Masoomi, M.; Yamini, Y.; Morsali, A.; Inorg. Chem. 2015, 54(2), 425-433, DOI: 10.1021/ic5015384
3) Bisht, K.; Suresh, E.; J. Am. Chem. Soc. 2013, 135(42), 15690-15693, DOI: 10.1021/ja4075369 ; Spontaneous Resolution to Absolute Chiral Induction: Pseudo-Kagomé Type Homochiral Zn(II)/Co(II) Coordination Polymers with Achiral Precursors
4) Yang, W.; Lin, X.; Blake, A.; Wilson, C.; Hubberstey, P.; Champness, N.; Schroder, M.; Inorg. Chem. 2009, 48(23), 11067-11078, DOI: 10.1021/ic901429u ; Self-Assembly of Metal-Organic Coordination Polymers Constructed from a Bent Dicarboxylate Ligand: Diversity of Coordination Modes, Structures, and Gas Adsorption
5) Zhou, J.; Du, L.; Qiao, Y.; Hu, Y.; Li, B.; Li, L.; Wang, X.; Yang, J.; Xie, M.; Zhao, Q.; Cryst. Growth Des. 2014, 14(3), 1175-1183, DOI: 10.1021/cg401692e ; Intriguing Architectures Generated from 1,4-Bis(3- or 4-pyridyl)-2,3-diaza-1,3-butadiene with Aromatic Dicarboxylates: Syntheses, Crystal Structures, and Properties
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