产品名称:2,2'-联吡啶-4,4'-二羧酸
其他名称:2,2'-bipyridyl-4,4'-dicarboxylic acid,[2,2'-Bipyridine]-4,4'-dicarboxylic acid ; H2dcbp; 4,4'-H2dcbp; BPDC
CAS:6813-38-3
其他名称:2,2'-bipyridyl-4,4'-dicarboxylic acid,[2,2'-Bipyridine]-4,4'-dicarboxylic acid ; H2dcbp; 4,4'-H2dcbp; BPDC
CAS:6813-38-3
结构信息
分子式 | C12H8N2O4 | 分子量 | 244.20292 | ||
性状照片 |
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料,如: [Ln(BPDC)1.5(DMF)(H2O)2] [r4] 等
表征图谱
参考文献
1) Tynan, Eithne; Jensen, Paul; Kruger, Paul E.; Lees, Anthea C.; Chem. Commun. 2004, (7), 776-777, DOI: 10.1039/B315483A ; Solvent templated synthesis of metal-organic frameworks: structural characterization and properties of the 3D network isomers {[Mn(dcbp)]·1/2DMF}n and {[Mn(dcbp)]·2H2O}n
2) Tynan, Eithne; Jensen, Paul; Kelly, Niamh R.; Kruger, Paul E.; Lees, Anthea C.; Moubaraki, Boujemaa; Murray, Keith S.; Dal. Trans. 2004, (21), 3440-3447, DOI: 10.1039/B408961H ; The ligand, the metal and the Holey'-host: Synthesis, structural and magnetic characterization of Co(II), Ni(II) and Mn(II) metal-organic frameworks incorporating 4,4'-dicarboxy-2,2'-bipyridine
3) Shi, Peng-Fei; Zhao, Bin; Xiong, Gang; Hou, Yin-Ling; Cheng, Peng; Chem. Commun. 2012, 48(66), 8231-8233, DOI: 10.1039/c2cc33707j ; Fast capture and separation of, and luminescent probe for, pollutant chromate using a multi-functional cationic heterometal-organic framework
4) Fang, Ming; Li, Ji-Jing; Shi, Peng-Fei; Zhao, Bin; Cheng, Peng; Dal. Trans. 2013, 42(18), 6553-6563, DOI: 10.1039/c3dt32861a ; Structures, luminescence, and slow magnetic relaxation of eight 3D lanthanide-organic frameworks
5) Li, Lina; Zhang, Shuquan; Xu, Liangjin; Han, Liang; Chen, Zhong-Ning; Luo, Junhua; Inorg. Chem. 2013, 52(21), 12323-12325, DOI: 10.1021/ic402158n ; An Intensely Luminescent Metal-Organic Framework Based on a Highly Light-Harvesting Dicyclo-Metalated Iridium(III) Unit Showing Effective Detection of Explosives
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