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2,2'-联吡啶-4,4'-二羧酸

[2,2'-Bipyridine]-4,4'-dicarboxylic acid

CAS NO.:6813-38-3分子式:C12H8N2O4分子量:244.20292
产品名称:2,2'-联吡啶-4,4'-二羧酸
其他名称:2,​2'-​bipyridyl-​4,​4'-​dicarboxylic acid,[2,2'-Bipyridine]-4,4'-dicarboxylic acid ; H2dcbp; 4,4'-H2dcbp; BPDC
CAS:6813-38-3
结构信息
分子式  C12H8N2O4 分子量  244.20292
性状照片
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料,如: [Ln(BPDC)​1.5(DMF)​(H2O)​2] [r4] 等
表征图谱
HNMR
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Tynan, Eithne; Jensen, Paul; Kruger, Paul E.; Lees, Anthea C.; Chem. Commun. 2004, (7), 776-777, DOI: 10.1039/B315483A ; Solvent templated synthesis of metal-​organic frameworks: structural characterization and properties of the 3D network isomers {[Mn(dcbp)​]​·1​/2DMF}​n and {[Mn(dcbp)​]​·2H2O}​n
2) Tynan, Eithne; Jensen, Paul; Kelly, Niamh R.; Kruger, Paul E.; Lees, Anthea C.; Moubaraki, Boujemaa; Murray, Keith S.; Dal. Trans. 2004, (21), 3440-3447, DOI: 10.1039/B408961H ; The ligand, the metal and the Holey'-​host: Synthesis, structural and magnetic characterization of Co(II)​, Ni(II) and Mn(II) metal-​organic frameworks incorporating 4,​4'-​dicarboxy-​2,​2'-​bipyridine
3) Shi, Peng-Fei; Zhao, Bin; Xiong, Gang; Hou, Yin-Ling; Cheng, Peng; Chem. Commun. 2012, 48(66), 8231-8233, DOI: 10.1039/c2cc33707j ; Fast capture and separation of, and luminescent probe for, pollutant chromate using a multi-​functional cationic heterometal-​organic framework
4) Fang, Ming; Li, Ji-Jing; Shi, Peng-Fei; Zhao, Bin; Cheng, Peng;  Dal. Trans. 2013, 42(18), 6553-6563, DOI: 10.1039/c3dt32861a ; Structures, luminescence, and slow magnetic relaxation of eight 3D lanthanide-​organic frameworks
5) Li, Lina; Zhang, Shuquan; Xu, Liangjin; Han, Liang; Chen, Zhong-Ning; Luo, Junhua; Inorg. Chem. 2013, 52(21), 12323-12325, DOI: 10.1021/ic402158n ; An Intensely Luminescent Metal-​Organic Framework Based on a Highly Light-​Harvesting Dicyclo-​Metalated Iridium(III) Unit Showing Effective Detection of Explosives
HNMR-6813-38-3-CS013214.pdf 下载

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