产品名称：4,4'-[1-cyclopentene-1,2-diylbis(5-methyl-4,2-thiophenediyl)]bis-pyridine
其他名称：BPMTC ; BPDTE；bis(5-pyridyl-2-methylthien-3-yl)cyclopentene
CAS：608528-49-0
其他名称：BPMTC ; BPDTE；bis(5-pyridyl-2-methylthien-3-yl)cyclopentene
CAS：608528-49-0
结构信息
| 分子式 | C25H22N2S2 | 分子量 | 414.58558 | ||
| 性状照片 |  |
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性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:Py-BTE [r2]; Metal-Porphyrin Frameworks porphyrin–BPMTC array [r4]; PC-PCN [r5];
表征图谱
参考文献
1) Qin, Bing; Yao, Rongxia; Zhao, Xueli; Tian, He; Org. & Biomole. Chem. 2003, 1(12), 2187-2191, DOI: 10.1039/b303028h ; Enhanced photochromism of 1,2-dithienylcyclopentene complexes with metal ion
2) Tian, He; Qin, Bing; Yao, Rongxia; Zhao, Xueli; Yang, Songjie; Adv. Mater. 2003, 15(24), 2104-2107, DOI: 10.1002/adma.200305425 ; A single photochromic molecular switch with four optical outputs probing four inputs
3) Xiao, Shuzhang; Zou, Ying; Wu, Juncheng; Zhou, Yifeng; Yi, Tao; Li, Fuyou; Huang, Chunhui; J. Mater. Chem. 2007, 17(24), 2483-2489, DOI: 10.1039/b701712j ; Hydrogen bonding assisted switchable fluorescence in self-assembled complexes containing diarylethene: controllable fluorescent emission in the solid state
4) Williams, Derek E.; Rietman, Joseph A.; Maier, Josef M.; Tan, Rui; Greytak, Andrew B.; Smith, Mark D.; Krause, Jeanette A.; Shustova, Natalia B.; Journal of the American Chemical Society 2014, 136(34), 11886-11889, DOI: 10.1021/ja505589d ; Energy Transfer on Demand: Photoswitch-Directed Behavior of Metal-Porphyrin Frameworks
5) Park, Jihye; Feng, Dawei; Yuan, Shuai; Zhou, Hong-Cai; Angew. Chem., Int. Ed. 2015, 54(2), 430-435, DOI: 10.1002/anie.201408862 ; Photochromic metal-organic frameworks: Reversible control of singlet oxygen generation
6) Dolgopolova, Ekaterina A.; Galitskiy, Vladimir A.; Martin, Corey R.; Gregory, Haley N.; Yarbrough, Brandon J.; Rice, Allison M.; Berseneva, Anna A.; Ejegbavwo, Otega A.; Stephenson, Kenneth S.; Kittikhunnatham, Preecha; Karakalos, Stavros G.; Smith, Mark D.; Greytak, Andrew B.; Garashchuk, Sophya; Shustova, Natalia B.; Journal of the American Chemical Society 2019, 141(13), 5350-5358, DOI: 10.1021/jacs.8b13853 ; Connecting wires: photoinduced electronic structure modulation in metal-organic frameworks
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