产品名称：1,3,5-Triazine, 2,4,6-tri-2-pyrimidinyl-
其他名称：TPymT
CAS：60681-68-7
其他名称：TPymT
CAS：60681-68-7
结构信息
| 分子式 | C15H9N9 | 分子量 | 315.292 | ||
| 性状照片 |  |
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性质说明
1) 可溶于水，微溶于DMF、DMSO等
2) 室温密封保存
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料，如：[Co(bpcam)2]ClO4·dmso·H2O [r3]; [Cd2(TPymT)(SO4)2(H2O)6] [r4]; [Ag2(BPymTz)2] [r5]
表征图谱
参考文献
1) Case, Francis H.; Koft, Emil; Journal of the American Chemical Society 1959, 81, 905-906, DOI: 10.1021/ja01513a037 ; The synthesis of certain substituted 1,3,5-triazines containing the ferroin group
2) Lerner, E. I.; Lippard, S. J.; Journal of the American Chemical Society 1976, 98(17), 5397-5398, DOI: 10.1021/ja00433a061 ; 2,4,6-Tris(2-pyrimidyl)- and 2,4,6-tris(2-pyridyl)-1,3,5-triazines hydrolyze in the presence of copper(II) to form a novel bis(aryl)carboximidato chelate complex
3) Garcia, Ana M.; Bassani, Dario M.; Lehn, Jean-Marie; Baum, Gerhard; Fenske, Dieter; Chemistry - A European Journal 1999, 5(4), 1234-1238, DOI: 10.1002/(SICI)1521-3765(19990401)5:4<1234::AID-CHEM1234>3.0.CO;2-G ; Self-assembly of multicomponent multimetallic lead(II) complexes of cylindrical architecture
4) Frost, Jamie M.; Kobera, Libor; Pialat, Amelie; Zhang, Yixin; Southern, Scott A.; Gabidullin, Bulat; Bryce, David L.; Murugesu, Muralee; Chem. Commun. 2016, 52(70), 10680-10683, DOI: 10.1039/C6CC04940K ; From discrete molecule, to polymer, to MOF: mapping the coordination chemistry of CdII using 113Cd solid-state NMR
5) Safin, Damir A.; Pialat, Amelie; Leitch, Alicea A.; Tumanov, Nikolay A.; Korobkov, Ilia; Filinchuk, Yaroslav; Brusso, Jaclyn L.; Murugesu, Muralee; Chem. Commun. 2015, 51(46), 9547-9550, DOI: 10.1039/C5CC01597A ; Anion-induced AgI self-assemblies with electron deficient aromatic ligands: anion-π-system interactions as a driving force for templated coordination networks
| 60681-68-7-CS017173.pdf | 下载 |
| 60681-68-7-CS017173-MS.pdf | 下载 |
