产品名称：N,N'-bis(4-pyridyl formamide)-1,4-benzene
其他名称：bpfb;
CAS：55119-42-1
其他名称：bpfb;
CAS：55119-42-1
结构信息
| 分子式 | C18H14N4O2 | 分子量 | 318.32936 | ||
| 性状照片 | |||||
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料：Hg(bpfb)I2 [r1] TMU-23 [r4]
表征图谱
参考文献
1) Niu, Y.; Song, Y.; Wu, J.; Hou, H.; Zhu, Y.; Wang, X.; Inorg. Chem. Commun. 2004, 7(4), 471-474, DOI: 10.1016/j.inoche.2004.01.006 ; Nonlinear polymeric effect: synthesis, crystal structure and nonlinear optical properties of a new mercury iodide adduct polymer [Hg(bpfb)I2]n · 2DMF (bpfb=N,N′-bis(4-pyridyl formamide)-1,4-benzene)
2) Sarkar, M.; Biradha, K.; Cryst. Growth Des 2006, 6(1), 202-208, DOI: 10.1021/cg050292l ; Amide-to-Amide Hydrogen Bonds in the Presence of a Pyridine Functionality: Crystal Structures of Bis(pyridinecarboxamido)alkanes
3) Luo, F.; Zheng, J.; Batten, S.; Chem. Commun. 2007, (36), 3744-3746, DOI:10.1039/b706177c ; Unprecedented (3,4)-connected metal–organic frameworks (MOFs) with 3-fold interpenetration and considerable solvent-accessible void space
4) Safarifard, V.; Rodriguez-Hermida, S.; Guillerm, V.; Imaz, I.; Bigdeli, M.; Tehrani, A.; Juanhuix, J.; Morsali, A.; Casco, M.; Silvestre-Albero, J.; Ramos-Fernandez, E.; Maspoch, D.; Cryst. Growth Des. 2016, 16, 10, 6016-6023, DOI: 10.1021/acs.cgd.6b01054 ; Influence of the Amide Groups in the CO2/N2 Selectivity of a Series of Isoreticular, Interpenetrated Metal-Organic Frameworks
