产品名称: 3,3',5,5'-Biphenyltetracarboxylicacid
其他名称: 3,3',5,5'-联苯四甲酸;H4BPTC
CAS: 4371-28-2
其他名称: 3,3',5,5'-联苯四甲酸;H4BPTC
CAS: 4371-28-2
结构信息
分子式 | C16H10O8 | 分子量 | 330.25 | ||
性状照片 |
性质说明
1) 4371-28-2 微溶于DMF、DMSO等
2) 室温密封保存
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:NOTT-100 [r4]/MOF-505; NOTT-300/MFM-300 [r2, r3]; InOF-1; UPC-5; NOTT-400(Sc); SNU-MIO; SNU-MI1; MOF-501(NbO); MOF-502(PtS) [r5]
表征图谱
参考文献
1) Mazik, M.; Koenig, A. J. Org. Chem. 2006, 71(20), 7854-7857, DOI: 10.1021/jo0610309 ; Recognition Properties of an Acyclic Biphenyl-Based Receptor toward Carbohydrates
2) Yang, S., Sun, J., Ramirez-Cuesta, A. et al. Nat. Chem. 2012, 4, 887–894. DOI: 10.1038/nchem.1457 ; Selectivity and direct visualization of carbon dioxide and sulfur dioxide in a decorated porous host
3) Krap, C. P.; Newby, R.; Dhakshinamoorthy, A.; García, H.; Cebula, I.; Easun, T. L.; Savage, M.; Eyley, J. E.; Gao, S.; Blake, A. J.; Lewis, W.; Beton, P. H.; Warren, M. R.; Allan, D. R.; Frogley, M. D.; Tang, C. C.; Cinque, G.; Yang, S.; Schröder, M. Inorg. Chem. 2016, 55, 1076– 1088, DOI: 10.1021/acs.inorgchem.5b02108 ; Enhancement of CO2 Adsorption and Catalytic Properties by Fe-Doping of [Ga2(OH)2(L)] (H4L = Biphenyl-3,3′,5,5′-tetracarboxylic Acid), MFM-300(Ga2)
4) Lin, X.; Telepeni, I.; Blake, A.; Dailly, A.; Brown, C.; Simmons, J.; Zoppi, M.; Walker, G.; Thomas, K.; Mays, T.; Hubberstey, P.; Champness, N.; Schroder, M.; J. Am. Chem. Soc. 2009, 131(6), 2159-2171, DOI: 10.1021/ja806624j ; High Capacity Hydrogen Adsorption in Cu(II) Tetracarboxylate Framework Materials: The Role of Pore Size, Ligand Functionalization, and Exposed Metal Sites
5) Chen, B.; Ockwig, N.; Fronczek, F.; Contreras, D.; Yaghi, O.; Inorg. Chem. 2005, 44(2), 181-183, DOI:10.1021/ic048612y ; Transformation of a Metal−Organic Framework from the NbO to PtS Net
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