产品名称：4,4′-Bi-3,5-dimethylpyrazole
其他名称：H2mdpz; Me4bpz;
CAS：4054-67-5
其他名称：H2mdpz; Me4bpz;
CAS：4054-67-5
结构信息
| 分子式 | C10H14N4 | 分子量 | 190.24496 | ||
| 性状照片 | |||||
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料：MAF-X11 ; SIFSIX-8 & SIFSIX-8-β [r7]
表征图谱
参考文献
1) Kruger, P.; Moubaraki, B.; Fallonb, G.; Murrayb, K.; J. Chem. Soc., Dalton Trans., 2000, 713-718, DOI: 10.1039/A908177A Tetranuclear copper(II) complexes incorporating short and long metal–metal separations: synthesis, structure and magnetism
2) Cuadro, A.; Elguero, J.; Navarro, P.; Chem. Pharm. Bull. 1985, 33(6), 2535-2540, DOI: 10.1248/cpb.33.2535. Binuclear pyrazoles. I. Synthesis and cytotoxic activity of 1,1'-dibenzyl and 1,1'-dihydroxymethyl 4,4'-bispyrazoles
3) Boldog, I.; Rusanov, E.; Chernega, A.; Sieler, J.; Domasevitch, K.; Polyhedron 2001, 20, 887-897, DOI: 10.1016/S0277-5387(01)00726-4 One- and two-dimensional coordination polymers of 3,3',5,5'-tetramethyl-4,4'-bipyrazolyl, a new perspective crystal engineering module
4) Hunger, J. Inorganica Chimica Acta 2013, 397, 60-68, DOI: 10.1016/j.ica.2012.11.019 Synthesis and structure of coordination polymers of Mn2+, Cu2+, Ag+, Zn2+ and Cd2+ by combination of bipyrazole and diphenate ligands
5) Zhang, E.; Jia, Q.; Zhang, J.; Ji, Z.; Chin. J. Chem. 2016, 34(2), 191-195, DOI: 10.1002/cjoc.201500640 Metal-Anion Coordination and Linker-Anion Hydrogen Bonding in the Construction of Metal-Organic Frameworks from Bipyrazole
6) Lin, Rui-Biao; Li, Fang; Liu, Si-Yang; Qi, Xiao-Lin; Zhang, Jie-Peng; Chen, Xiao-Ming; Angew. Chem., Int. Ed. 2013, 52(50), 13429-13433, DOI: 10.1002/anie.201307217 ; A Noble-Metal-Free Porous Coordination Framework with Exceptional Sensing Efficiency for Oxygen
7) SOUMYA MUKHERJEE , NIVEDITA SIKDAR, DANIEL O’NOLAN , DOUGLAS M. FRANZ, VICTORIA GASCÓN , AMRIT KUMAR , NAVEEN KUMAR , HAYLEY S. SCOTT, DAVID G. MADDEN , PAUL E. KRUGER , MICHAEL J. ZAWOROTKO, SCIENCE ADVANCES 2019, 5, 11, eaax 9197, DOI: 10.1126/sciadv.aax9171 ; Trace CO2 capture by an ultramicroporous physisorbent with low water affinity
