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N,N,N',N'-四(对氨基苯基)对苯二胺

N,N,N',N'-Tetrakis(4-aminophenyl)-1,4-benzenediamine

CAS NO.:3283-07-6分子式:C30H28N6分子量:472.58352
产品名称:N,N,N',N'-Tetrakis(4-aminophenyl)-1,4-benzenediamine
其他名称:N,N,N',N'-四(对氨基苯基)对苯二胺 ; TPPDA ; TPBD ; TAPD
CAS:3283-07-6
结构信息
分子式  C30H28N6 分子量  472.58352
性状照片  
性质说明
1) 3283-07-6 可溶于DCM、DMF、DMSO等
2) 室温密封保存
合成应用
1)可作为单体用于合成COF材料,如:TPPDA-TPPyr, TPPDA-TPTPE COFs [r1]; EC-Cof-1 [r3]; TAPD-(Me)2, TAPD-(OMe)2 COFs [r4]
表征图谱
HNMR
MS
NA
FTIR
NA
HPLC
NA
参考文献
1)  El-Mahdy, Ahmed F. M.; Mohamed, Mohamed Gamal; Mansoure, Tharwat Hassan; Yu, Hsiao-Hua; Chen, Tao; Kuo, Shiao-Wei; Chem. Commun. 2019, 55(99), 14890-14893, DOI: 10.1039/c9cc08107k ; Ultrastable tetraphenyl-​p-​phenylenediamine-​based covalent organic frameworks as platforms for high-​performance electrochemical supercapacitors
2) Rotter, Julian M.; Guntermann, Roman; Auth, Michael; Maehringer, Andre; Sperlich, Andreas; Dyakonov, Vladimir; Medina, Dana D.; Bein, Thomas; Chem. Sci. 2020, 11(47), 12843-12853, DOI: 10.1039/d0sc03909h ; Highly conducting Wurster-​type twisted covalent organic frameworks
3) u, Fei; Liu, Wenbo; Ke, Si-Wen; Kurmoo, Mohamedally; Zuo, Jing-Lin; Zhang, Qichun; Nature Commun. 2020, 11(1), 5534, DOI: 10.1038/s41467-020-19315-6 ;  Electrochromic two-​dimensional covalent organic framework with a reversible dark-​to-​transparent switch
4) Krishnaraj, Chidharth; Sekhar Jena, Himanshu; Bourda, Laurens; Laemont, Andreas; Pachfule, Pradip; Roeser, Jerome; Chandran, C. Vinod; Borgmans, Sander; Rogge, Sven M. J.; Leus, Karen; Stevens, Christian V.; Martens, Johan A.; Van Speybroeck, Veronique; Breynaert, Eric; Thomas, Arne; Van Der Voort, Pascal; Journal of the American Chemical Society 2020, 142(47), 20107-20116, DOI: 10.1021/jacs.0c09684 ; Strongly Reducing (Diarylamino)​benzene-​Based Covalent Organic Framework for Metal-​Free Visible Light Photocatalytic H2O2 Generation
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