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4'-(3-pyridinyl)-2,2':6',2''-Terpyridine

2,2':6',2''-Terpyridine, 4'-(3-pyridinyl)-

CAS NO.:311341-20-5分子式:C20H14N4分子量:310.35196
产品名称:4'-​(3-​Pyridinyl)​-​2,​2':6',​2''-​terpyridine
其他名称:3-​pytpy ; 3-​py-​tpy;
CAS:311341-20-5
结构信息
 
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:[Cd(bdc)​(3-​pytpy)​]​n [r4]; ([M(3-​py-​tpy)​2]​X2 [r5]
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Goodall, Wendy; Williams, J. A. Gareth; Dalton 2000, (17), 2893-2895, Iridium(III) bis-​terpyridine complexes incorporating pendent N-​methylpyridinium groups: luminescent sensors for chloride ions
2) Smith, Christopher B.; Raston, Colin L.; Sobolev, Alexandre N.; Green Chem. 2005, 7(9), 650-654, DOI: 10.1039/b507581p ; Poly(ethyleneglycol) (PEG)​: a versatile reaction medium in gaining access to 4'-​(pyridyl)​-​terpyridines
3) Feng, Hua; Zhou, Xiao-Ping; Wu, Tao; Li, Dan; Yin, Ye-Gao; Ng, Seik Weng; Inorg.Chimi. Acta 2006, 359(12), 4027-4035, DOI: 10.1016/j.ica.2006.04.035 ; Hydrothermal synthesis of copper complexes of 4'-​pyridylterpyridine: From discrete monomer to zigzag chain polymer
4) Li, Na; Gou, Lei; Hu, Huai-Ming; Chen, Shuan-Hu; Chen, Xiao-Li; Wang, Bao-Cheng; Wu, Qing-Ran; Yang, Meng-Lin; Xue, Gang-Lin;Inorg.Chimi. Acta 2009, 362(10), 3475-3483, DOI: 10.1016/j.ica.2009.03.033 ; The effect of organic acid on self-​assembly process: Syntheses and characterizations of six novel cadmium(II)​/zinc(II) complexes derived from mixed ligands

5) Pal, Amlan K.; Laramee-Milette, Baptiste; Hanan, Garry S.;Inorg.Chimi. Acta 2014, 418, 15-22, DOI: 10.1016/j.ica.2014.04.012 ; One- and two-​dimensional polymerisation of homoleptic M(II)​-​complexes of 4'-​(3-​pyridyl)​-​2,​2';6',​2''-​terpyridine in the solid state: A combined study by XRD, cyclic voltammetry, NMR and UV-​Vis spectroscopies

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