产品名称：1,2-Bis(1,2,4-triazol-4-yl)ethane其他名称：BTRE ; tr2eth;4,4'-(1,2-Ethanediyl)bis[4H-1,2,4-triazole] CAS：260251-70-5
结构信息
| 分子式 |
C6H8N6 |
分子量 |
164.16792 |
| 性状照片 |
|
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:[Cu3(btre)5(H2O)2] [r1]; Zn2Cl4(μ2-btre)2] [r2]; ISE-1 framework [r3]; [Ag2(VO2F2)2(tr2ad)2] [r5]
表征图谱
参考文献
1) Carcia, Yann; Van Koningsbruggen, Petra J.; Kooijman, Huub; Spek, Anthony L.; Haasnoot, Jaap G.; Kahn, Olivier; Eur. J. Inorg. Chem. 2000, (2), 307-314, Synthesis, crystal structure, spectroscopic and magnetic properties of an unprecedented three-dimensional Cu(II) coordination compound of 1,2-bis(1,2,4-triazol-4-yl)ethane
2) Habib, Hesham A.; Hoffmann, Anke; Hoppe, Henning A.; Steinfeld, Gunther; Janiak, Christoph; Inorg. Chem. 2009, 48(5), 2166-2180, DOI: 10.1021/ic802069k ; Crystal Structure Solid-State Cross Polarization Magic Angle Spinning 13C NMR Correlation in Luminescent d10 Metal-Organic Frameworks Constructed with the 1,2-Bis(1,2,4-triazol-4-yl)ethane Ligand
3) enninger, Stefan K.; Habib, Hesham A.; Janiak, Christoph; Journal of the American Chemical Society 2009, 131(8), 2776-2777, DOI: 10.1021/ja808444z ; MOFs as Adsorbents for Low Temperature Heating and Cooling Applications
4) Cui, Yan-Feng; Qian, Xin; Chen, Qian; Li, Bao-Long; Li, Hai-Yan; CrystEngComm 2012, 14(4), 1201-1204, DOI:1 0.1039/C2CE06397B ; A polythreading coordination array formed from a 3D microporous cation network and 1D anion ladders
5) Senchyk, Ganna A.; Bukhan'ko, Valeriy O.; Lysenko, Andrey B.; Krautscheid, Harald; Rusanov, Eduard B.; Chernega, Alexandr N.; Karbowiak, Miroslaw; Domasevitch, Konstantin V.; Inorg. Chem. 2012, 51(15), 8025-8033, DOI: 10.1021/ic3000894 ; AgI/VV Heterobimetallic Frameworks Generated from Novel-Type {Ag2(VO2F2)2(triazole)4} Secondary Building Blocks: A New Aspect in the Design of SVOF Hybrids6) Habib, Hesham A.; Sanchiz, Joaquin; Janiak, Christoph; Dalton Trans 2008, (13), 1734-1744, DOI: 10.1039/b715812b ; Mixed-ligand coordination polymers from 1,2-bis(1,2,4-triazol-4-yl)ethane and benzene-1,3,5-tricarboxylate: Trinuclear nickel or zinc secondary building units for three-dimensional networks with crystal-to-crystal transformation upon dehydration
