产品名称: 2,5-Disulfanylterephthalic acid
其他名称: 对巯基对苯二甲酸;H2DMBD; H4DSBDC
CAS: 25906-66-5
其他名称: 对巯基对苯二甲酸;H2DMBD; H4DSBDC
CAS: 25906-66-5
结构信息
分子式 | C8H6O4S2 | 分子量 | 230.26084 | ||
性状照片 |
性质说明
1) 25906-66-5 溶于DMF、DMSO等
2) 室温密封保存
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:Zr-DMBD [r2], Mn2(DSBDC) [r3]; Fe2(DSBSC); UiO-66-SH [r5]
表征图谱
参考文献
1) Field, L.; Engelhardt, P. R. J. Org. Chem. 1970, 35, 3647-3655
2) Yee, K.-K.; Reimer, N.; Liu, J.; Cheng, S.-Y.; Yiu, S.-M.; Weber, J.; Stock, N.; Xu, Z.; J. Am. Chem. Soc. 2013, 135, 7795-7798, DOI:10.1021/ja400212k ; Effective Mercury Sorption by Thiol-Laced Metal–Organic Frameworks: in Strong Acid and the Vapor Phase
3) Sun, L.; Miyakai, T.; Seki, S.; Dinca, M.; J. Am. Chem. Soc. 2013, 135(22), 8185-8188, DOI:10.1021/ja4037516 ; Mn2(2,5-disulfhydrylbenzene-1,4-dicarboxylate): A Microporous Metal–Organic Framework with Infinite (−Mn–S−)∞ Chains and High Intrinsic Charge Mobility
4) Sun, L.; Hendon, C.; Minier, M.; Walsh, A.; Dinca, M.; J. Am. Chem. Soc. 2015, 137(19), 6164-6167, DOI:10.1021/jacs.5b02897 ; Million-Fold Electrical Conductivity Enhancement in Fe2(DEBDC) versus Mn2(DEBDC) (E = S, O)
5) Phang, W.; Jo, H.; Lee, W.; Song, J.; Yoo, K.; Kim, B.; Hong, C.; Angew. Chem., Int. Ed. 2015, 54(17), 5142-5146, DOI:10.1002/anie.201411703; Superprotonic Conductivity of a UiO‐66 Framework Functionalized with Sulfonic Acid Groups by Facile Postsynthetic Oxidation