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四(3,5-二羧基苯基)卟啉

1,​3-​Benzenedicarboxylic acid, 5,​5',​5'',​5'''-​(21H,​23H-​porphine-​5,​10,​15,​20-​tetrayl)​tetrakis-

CAS NO.:253195-52-7分子式:C52H30N4O16分子量:966.8118
产品名称:5,​10,​15,​20-​tetrakis(3,​5-​dicarboxyphenyl)​porphyrin
其他名称:tdcpp;tetrakis(3,​5-​dicarboxyphenyl)​porphine
CAS:253195-52-7
结构信息
分子式 C52H30N4O16 分子量  966.8118
性状照片  
性质说明
1) 253195-52-7 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:PrMPF-​1/2 [r3] ;  MMPF-​2 /4/5 [r2, r4]
2) 可用于合成液晶材料
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Patel, Bimal R.; Suslick, Kenneth S.; J. Am. Chem. Soc. 1998, 120(45), 11802-11803, DOI: 10.1021/ja9820689 ; Discotic Liquid Crystals from a Bis-Pocketed Porphyrin 
2) Wang, Xi-Sen; Chrzanowski, Matthew; Kim, Chungsik; Gao, Wen-Yang; Wojtas, Lukasz; Chen, Yu-Sheng; Peter Zhang, X.; Ma, S. Chem. Commun. 2012, 48(57), 7173-7175  DOI: 10.1039/C2CC33118G ; Quest for highly porous metal–metalloporphyrin framework based upon a custom-designed octatopic porphyrin ligand 
3) Tripuramallu, B.; Goldberg, I.  Cryst. Growth Des. 2016, 16(3), 1751-1764, DOI: 10.1021/acs.cgd.6b00028 ; Assembling Coordination Frameworks of Tetrakis[meso-(3,5-biscarboxyphenyl)]-Metalloporphyrins with Polynuclear Metallic Nodes: Mechanistic Insights into the Synthesis and Crystallization Process 
4) Wang, X.; Chrzanowski, M.; Gao, W.; Wojtas, L.; Chen, Y.; Zaworotko, M.; Ma, S.; Chem. Sci. 2012, 3(9), 2823-2827, DOI: 10.1039/c2sc20330h

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