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4,4'-磺酰基二苯甲酸

Benzoic acid,4,4'-sulfonylbis-

CAS NO.:2449-35-6分子式:C14H10O6S分子量:306.290603160858
产品名称:4,4'-sulfonylbis-Benzoic acid
其他名称:H2SDB; H2DCPS ; 4,​4'-​Sulfonylbis[benzoic acid]​; 4,​4'-​Dicarboxydiphenyl sulfone; 4,​4'-​Sulfonyldibenzoic acid; Bis(4-​carboxyphenyl) sulfone; Diphenylsulfone-​4,​4'-​dicarboxylic acid
CAS:2449-35-6
结构信息
分子式 C14H10O6S 分子量 306.2906
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料: MOF-114 [r2]; IITKGP-​6 [r4] ; CYCU-​1 / Ca(SBA) [r5]; [Al(OH)​(SDBA)​] / CAU-11 [r6];
表征图谱
HNMR
MS
NA
FTIR
NA
HPLC
NA
参考文献
 1) Boyarskii, V. P.; Zhesko, T. E.; Lanina, S. A.; Russ. J. Appl. Chem. 2005, 78, 1844-1848, DOI: 10.1007/s11167-005-0619-y ; Synthesis of Aromatic Carboxylic Acids by Carbonylation of Aryl Halides in the Presence of Epoxide-​Modified Cobalt Carbonyls as Catalysts
2) Furukawa, Hiroyasu; Kim, Jaheon; Ockwig, Nathan W.; O'Keeffe, Michael; Yaghi, Omar M.; J. Am. Chem. Soc. 2008, 130(35), 11650-11661, DOI: 10.1021/ja803783c ; Control of Vertex Geometry, Structure Dimensionality, Functionality, and Pore Metrics in the Reticular Synthesis of Crystalline Metal-​Organic Frameworks and Polyhedra
3) Chen, Shuguang; Shi, Zhenzhen; Qin, Ling; Jia, Hailang; Zheng, Hegen; Cryst. Growth & Des. 2017, 17(1), 67-72, DOI: 10.1021/acs.cgd.6b01197 ; Two New Luminescent Cd(II)​-​Metal-​Organic Frameworks as Bifunctional Chemosensors for Detection of Cations Fe3+, Anions CrO42-​, and Cr2O72- in Aqueous Solution
4) Pal, Arun; Chand, Santanu; Das, Madhab C.; Inorg. Chem. 2017, 56(22), 13991-13997, DOI: 10.1021/acs.inorgchem.7b02136 ; A Water-​Stable Twofold Interpenetrating Microporous MOF for Selective CO2 Adsorption and Separation
5) Yeh, Chun-Ting; Lin, Wei-Cheng; Lo, Sheng-Han; Kao, Ching-Che; Lin, Chia-Her; Yang, Chun-Chuen; CrystEngComm 2012, 14(4), 1219-1222, DOI: 10.1039/c2ce05875h ; Microwave synthesis and gas sorption of calcium and strontium metal-​organic frameworks with high thermal stability
6) Reimer, Nele; Reinsch, Helge; Inge, A. Ken; Stock, Norbert; Inorg. Chem. 2015, 54(2), 492-501, DOI: 10.1021/ic502242j ; New Al-​MOFs Based on Sulfonyldibenzoate Ions: A Rare Example of Intralayer Porosity
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