材料名称:CuHHTP
其他名称:Cu-HHTP ; Cu3(HHTP)2 ; Cu-CAT-1
CAS:2257422-27-6 / 1395994-19-0
其他名称:Cu-HHTP ; Cu3(HHTP)2 ; Cu-CAT-1
CAS:2257422-27-6 / 1395994-19-0
结构信息
单位分子式 | C36H12O12Cu3 | 单位分子量 | 827.11128 | ||
配位金属 | Cu | 配体 | 2,3,6,7,10,11-六羟基三苯 2,3,6,7,10,11-Triphenylenehexol(CAS:4877-80-9) | ||
孔径 | 1.8 nm | 孔容 | |||
比表面 | BET比表面 200 m2/g | ||||
模拟结构 |
产品性状
产品形貌 | 深褐(黑)色粉末 | |||
粒径 | 50-200nm |
稳定性
1) CuHHTP在空气中稳定数月,在水和常见有机溶剂中结构稳定数周
2)热分解温度约200℃
2)热分解温度约200℃
保存和活化方法
1) 常温或低温条件下,干燥密封保存
2) 80度(真空)烘箱活化10小时
2) 80度(真空)烘箱活化10小时
其他特性
荧光:NA
应用领域
1) Cu-THQ具有良好的电导率,可作为电极电容材料
2) Cu价态在充放电循环中发生变化,具有潜在的电催化或氧化还原反应能力
2) Cu价态在充放电循环中发生变化,具有潜在的电催化或氧化还原反应能力
表征图谱
参考文献
1) Hmadeh, Mohamad; Lu, Zheng; Liu, Zheng; Gandara, Felipe; Furukawa, Hiroyasu; Wan, Shun; Agustyn, Veronica; Chang, Rui; Liao, Lei; Zhou, Fei; Perre, Emilie; Ozolins, Vidvuds; Duan, Xiangfeng; Dunn, Bruce; Yamamto, Yasuaki; Terasaki, Osamu; Yaghi, Omar M.; Chem. Mater. 2012, 24(18), 3511-3513, DOI: 10.1021/cm301194a ; New Porous Crystals of Extended Metal-Catecholates
2) Yao, Ming-Shui; Lv, Xiao-Jing; Fu, Zhi-Hua; Li, Wen-Hua; Deng, Wei-Hua; Wu, Guo-Dong; Xu, Gang; Angew. Chem., Int. Ed. 2017, 56(52), 16510-16514, DOI:10.1002/anie.201709558 ; Layer-by-Layer Assembled Conductive Metal-Organic Framework Nanofilms for Room-Temperature Chemiresistive Sensing
3) Rubio-Gimenez, Victor; Almora-Barrios, Neyvis; Escorcia-Ariza, Garin; Galbiati, Marta; Sessolo, Michele; Tatay, Sergio; Marti-Gastaldo, Carlos; Angew. Chem., Int. Ed. 2018, 57(46), 15086-15090, DOI: 10.1002/anie.201808242 ; Origin of the Chemiresistive Response of Ultrathin Films of Conductive Metal-Organic Frameworks
4) Song, Xiaoyu; Wang, Xinyue; Li, Yusen; Zheng, Chengzhi; Zhang, Bowen; Di, Chong-an; Li, Feng; Jin, Chao; Mi, Wenbo; Chen, Long; Hu, Wenping; Angew. Chem., Int. Ed. 2020, 59, 1118-1123, DOI: 10.1002/anie.201911543 ; 2D Semiconducting Metal–Organic Framework Thin Films for Organic
Spin Valves