其他名称:TTA-DHTA COF;TAT-DHBD COF;TzDa COF;1,4-Benzenedicarboxaldehyde, 2,5-dihydroxy-, polymer with 4,4',4''-(1,3,5-triazine-2,4,6-triyl)tris[benzenamine]
单位分子式 | C21H18N6.C8H6O4 | 单位分子量 | 520.53866 | ||
单体 |
1)2,5-Diformylbenzene-1,4-diol (CAS: 1951-36-6) 2) (1,3,5-tris-(4-aminophenyl)triazine (CAS:14544-47-9) |
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孔径 | 26.1 和 37.9 Å | 孔容 | 0.44 cm³/g | ||
比表面 | BET比表面积约为600-800 | ||||
模拟结构 |
产品形貌 |
橘黄色固体 |
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粒径 |
2) 气体吸附测试前,建议使用前120度(真空)烘箱活化12小时
1)Qing Xu, Yanping Tang, Lipeng Zhai, Qiuhong Chen and Donglin Jiang *; Chem. Commun., 2017,53, 11690-11693; DOI: 10.1039/c7cc07002k; Pyrolysis of covalent organic frameworks: a general strategy for template converting conventional skeletons into conducting microporous carbons for high-performance energy storage【文献解读】;
2) Xiaofang Zhao, Junchang Chen, Xuanzhi Mao, Chunyang Li, Linwei He, Fan Zhang, Mingxing Zhang,* Juan Diwu, Guozhong Wu, Zhifang Chai, and Shuao Wang*; Inorg. Chem. 2024, 63, 26, 12333–12341; DOI:10.1021/acs.inorgchem.4c01788; One-Pot Synthesis of a Mixed-Valent Copper(I/II)-Coordinated Covalent Organic Framework Induced by γ-Ray Radiation【文献解读】;