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N,N-二(2-吡啶甲基)乙二胺

N,N-bis(2-pyridinylmethyl)-1,2-Ethanediamine

CAS NO.:189440-33-3分子式:C14H18N4分子量:242.31952
产品名称:N,N-bis(2-pyridinylmethyl)-1,2-Ethanediamine
其他名称:DPEA ; BPEA
CAS:189440-33-3
结构信息
分子式  C14H18N4 分子量  242.31952
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为中间体用于合成MOF材料配体或COF材料单体:Fe(DPEA)​(NCS)​2 [r1]   
2) 可用于荧光探针:ZnAF-​1F [r2]
表征图谱
HNMR
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Matouzenko, Galina S.; Bousseksou, Azzedine; Lecocq, Sylvain; van Koningsbruggen, Petra J.; Perrin, Monique; Kahn, Olivier; Collet, Andre; Inorg. Chem. 1997, 36(14), 2975-2981, DOI: 10.1021/IC9615133 ; Spin Transition in [Fe(DPEA)​(NCS)​2]​, a Compound with the New Tetradentate Ligand (2-​Aminoethyl)​bis(2-​pyridylmethyl)​amine (DPEA)​: Crystal Structure, Magnetic Properties, and Mossbauer Spectroscopy
2) Hirano, Tomoya; Kikuchi, Kazuya; Urano, Yasuteru; Nagano, Tetsuo; Journal of the American Chemical Society 2002, 124(23), 6555-6562, DOI: 10.1021/ja025567p [r2] ; Improvement and Biological Applications of Fluorescent Probes for Zinc, ZnAFs
3) Zhang, Changli; Liu, Zhipeng; Li, Yunling; He, Weijiang; Gao, Xiang; Guo, Zijian; Chem. Commun. 2013, 49(97), 11430-11432, DOI: 10.1039/c3cc46862c ; In vitro and in vivo imaging application of a 1,​8-​naphthalimide-​derived Zn2+ fluorescent sensor with nuclear envelope penetrability
4) Xu, Qin-Chao; Zhu, Xue-Hui; Jin, Can; Xing, Guo-Wen; Zhang, Yuan; RSC Adv. 2014, 4(7), 3591-3596, DOI: 10.1039/C3RA45717F ; Dual off-​on and on-​off fluorescent detection of Zn2+​/Cd2+ ions based on carbazolone substituted 2-​aminobenzamides
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