材料名称：TpBpy COF
其他名称：1,3,5-Benzenetricarboxaldehyde, 2,4,6-trihydroxy-, polymer with 1,4-benzenediamine
CAS：1414350-37-0
其他名称：1,3,5-Benzenetricarboxaldehyde, 2,4,6-trihydroxy-, polymer with 1,4-benzenediamine
CAS：1414350-37-0
结构信息
| 单位分子式 | C9H6O6.C6H8N2 | 单位分子量 | 318.28146 | ||
| 单体 |
2,4,6-trihydroxy-1,3,5-benzenetricarbaldehyde (CAS:34374-88-4); [2,2′-Bipyridine]-5,5′-diamine (CAS: 52382-48-6) |
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| 孔径 | 2.1nm | 孔容 | / | ||
| 比表面 | BET比表面400-600m2/g | ||||
| 模拟结构 | |||||
产品性状
| 产品形貌 |
深红色或褐色粉末 Dark Red or brown solid |
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| 粒径 | 不规则纳米颗粒团聚体 | |||
稳定性
1) 水溶液和酸性环境下稳定，强碱性条件下不稳定
保存和活化方法
1) 常温或低温条件下，干燥密封保存
其他特性
荧光:NA
应用领域
1) 用于气体和污染物吸附
2) 良好的孔道结合联吡啶的配位点可用于负载催化剂，尤其是金属催化剂
2) 良好的孔道结合联吡啶的配位点可用于负载催化剂，尤其是金属催化剂
表征图谱
参考文献
1) Shinde, Digambar Balaji; Aiyappa, Harshitha Barike; Bhadra, Mohitosh; Biswal, Bishnu P.; Wadge, Pritish; Kandambeth, Sharath; Garai, Bikash; Kundu, Tanay; Kurungot, Sreekumar; Banerjee, Rahul
Journal of Materials Chemistry A 2016, 4(7), 2682-2690, DOI: 10.1039/c5ta10521h ; A mechanochemically synthesized covalent organic framework as a proton-conducting solid electrolyte
2) Sun, Qi; Aguila, Briana; Perman, Jason; Nguyen, Nicholas; Ma, Shengqian; Journal of the American Chemical Society 2016, 138(48), 15790-15796, DOI: 10.1021/jacs.6b10629 ; Flexibility Matters: Cooperative Active Sites in Covalent Organic Framework and Threaded Ionic Polymer
3) Sasmal, Himadri Sekhar; Aiyappa, Harshitha Barike; Bhange, Siddheshwar N.; Karak, Suvendu; Halder, Arjun; Kurungot, Sreekumar; Banerjee, Rahul; Angewandte Chemie, International Edition 2018, 57(34), 10894-10898, DOI: 10.1002/anie.201804753 ; Superprotonic Conductivity in Flexible Porous Covalent Organic Framework Membranes
4) Zhong, Wanfu; Sa, Rongjian; Li, Liuyi ; He, Yajun; Li, Lingyun ; Bi, Jinhong ; Zhuang, Zanyong ; Yu, Yan ; Zou, Zhigang; Journal of the American Chemical Society 2019, 141(18), 7615-7621, DOI: 10.1021/jacs.9b02997 ; A Covalent Organic Framework Bearing Single Ni Sites as a Synergistic Photocatalyst for Selective Photoreduction of CO2 to CO
5) Peng Gao, Yezi Hu, Zewen Shen, Guixia Zhao, Ruiqing Cai, Feng Chu, Zhuoyu Ji, Xiangke Wang & Xiubing Huang; Nat Commun 15, 6700 2024 ; DOI：10.1038/s41467-024-50951-4;Ultra-highly efficient enrichment of uranium from seawater via studtite nanodots growth-elution cycle; 文献解读
6) Islam E. Khalil, Prasenjit Das, Hüseyin Küçükkeçeci, Veit Dippold, Jabor Rabeah, Warisha Tahir, Jérôme Roeser, Johannes Schmidt, and Arne Thomas*; Chem. Mater. 2024; DOI：10.1021/acs.chemmater.4c01298; Hierarchical Porous Covalent Organic Frameworks: The Influence of Additional Macropores on Photocatalytic Hydrogen Evolution and Hydrogen Peroxide Production;文献解读
