产品名称：Potassium hydrotris(pyrazolyl)borate
其他名称：KBPyz3;Borate(1-), hydrotris(1H-pyrazolato-N1)-, potassium, (T-4)-; Borate(1-), hydrotris(1H-pyrazolato-κN1)-, potassium, (T-4)- (9CI); Borate(1-), hydrotris(pyrazolato)-, potassium (8CI); 1H-Pyrazole, boron complex; Potassium hydridotris(1-pyrazolyl)borate; Potassium hydrotripyrazolylborate; Potassium hydrotris(1-pyrazolyl)borate; Potassium hydrotris(1-pyrazolyl)borate(1-); Potassium hydrotris(1H-pyrazol-1-yl)borate; Potassium hydrotris(pyrazol-1-yl)borate; Potassium hydrotris(pyrazolato)borate; Potassium hydrotris(pyrazolato)borate(1-);
CAS：18583-60-3
3) Comito, Robert J.; Wu, Zhenwei; Zhang, Guanghui; Lawrence, John A. III; Korzynski, Maciej D.; Kehl, Jeffrey A.; Miller, Jeffrey T.; Dinca, Mircea; Angew. Chem., Int. Ed. 2018, 57(27), 8135-8139, DOI: 10.1002/anie.201803642 ; Stabilized Vanadium Catalyst for Olefin Polymerization by Site Isolation in a Metal-Organic Framework
4) Murtuza, Shahid; Casagrande, Osvaldo L., Jr.; Jordan, Richard F.; Organometallics 2002, 21(9), 1882-1890, DOI: 10.1021/om010530j ; Ethylene Polymerization Behavior of Tris(pyrazolyl)borate Titanium(IV) Complexes
其他名称：KBPyz3;Borate(1-), hydrotris(1H-pyrazolato-N1)-, potassium, (T-4)-; Borate(1-), hydrotris(1H-pyrazolato-κN1)-, potassium, (T-4)- (9CI); Borate(1-), hydrotris(pyrazolato)-, potassium (8CI); 1H-Pyrazole, boron complex; Potassium hydridotris(1-pyrazolyl)borate; Potassium hydrotripyrazolylborate; Potassium hydrotris(1-pyrazolyl)borate; Potassium hydrotris(1-pyrazolyl)borate(1-); Potassium hydrotris(1H-pyrazol-1-yl)borate; Potassium hydrotris(pyrazol-1-yl)borate; Potassium hydrotris(pyrazolato)borate; Potassium hydrotris(pyrazolato)borate(1-);
CAS：18583-60-3
结构信息
| 分子式 | C9H10BN6-.K+ | 分子量 | 252.1252 | ||
| 性状照片 | |||||
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料：Poly(1-pyrazolyl)-borates
表征图谱
参考文献
1) Trofimenko, Swiatoslaw; J. Am. Chem. Soc. 1967, 89(13), 3170-3177, DOI: 10.1021/ja00989a017 ; Boron-pyrazole chemistry. II. Poly(1-pyrazolyl)-borates
2) Sohrin, Yoshiki; Kokusen, Hisao; Kihara, Sorin; Matsui, Masakazu; Kushi, Yoshihiko; Shiro, Motoo; J. Am. Chem. Soc. 1993, 115(10), 4128-4136, DOI: 10.1021/ja00063a034 ; New mode of ion size discrimination for Group 2 metals using poly(pyrazolyl)borate ligands. Control of stability and structure of chelate complexes by intraligand contact
