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2,3,6,7,10,11-Hexakis(4-carboxyphenyl)triphenylene

2,3,6,7,10,11-Hexakis(4-carboxyphenyl)triphenylene

CAS NO.:1821122-35-3分子式:C60H36O12分子量:948.9207
产品名称:4,​4',​4'',​4''',​4'''',​4'''''-​(2,​3,​6,​7,​10,​11-​triphenylenehexayl)​hexakisBenzoic acid,
其他名称:TP ; H6TPHB;Benzoic acid, 4,​4',​4'',​4''',​4'''',​4'''''-​(2,​3,​6,​7,​10,​11-​triphenylenehexayl)​hexakis-
CAS:1821122-35-3
结构信息
分子式 C60H36O12 分子量 948.92064
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:hydrogen-​bonded hexagonal network (H-​HexNet): Tp-1 [r2]; BUT-46A-F [r3]
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Hisaki, Ichiro; Ikenaka, Nobuaki; Tohnai, Norimitsu; Miyata, Mikiji; Chemical Communications 2016, 52(2), 300-303, DOI: 10.1039/C5CC07690K ; Polymorphs of layered assemblies of hydrogen-​bonded hexagonal networks caused by conformational frustration
2) Hisaki, Ichiro; Nakagawa, Shoichi; Ikenaka, Nobuaki; Imamura, Yutaka; Katouda, Michio; Tashiro, Motomichi; Tsuchida, Hiromu; Ogoshi, Tomoki; Sato, Hiroyasu; Tohnai, Norimitsu; Miyata, Mikiji; DOI: 10.1021/jacs.6b02968 ; A Series of Layered Assemblies of Hydrogen-​Bonded, Hexagonal Networks of C3-​Symmetric π-​Conjugated Molecules: A Potential Motif of Porous Organic Materials
3) Zhang, Yong-Zheng; He, Tao; Kong, Xiang-Jing; Lv, Xiu-Liang; Wu, Xue-Qian; Li, Jian-Rong; ACS Applied Materials & Interfaces 2018, 10(33), 27868-27874, DOI: 10.1021/acsami.8b09333 ; Tuning Water Sorption in Highly Stable Zr(IV)​-​Metal-​Organic Frameworks through Local Functionalization of Metal Clusters
4) Dai, Hongliang; Wang, Shuai; Hisaki, Ichiro; Nakagawa, Shoichi; Ikenaka, Nobuaki; Deng, Ke; Xiao, Xunwen; Zeng, Qingdao; Chemistry - An Asian Journal (2017), 12(19), 2558-2564, DOI: 10.1002/asia.201700749 ; On-​Surface Self-​Assembly of a C3-​Symmetric π-​Conjugated Molecule Family Studied by STM: Two-​Dimensional Nanoporous Frameworks

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