COF-367-Co

材料名称：COF-367-Co
其他名称：Cobalt, [[4,4′,4′′,4′′′-(21H,23H-porphine-5,10,15,20-tetrayl-κN21,κN22,κN23,κN24)tetrakis[benzenaminato]](2-)]-, (SP-4-1)-, polymer with [1,1′-biphenyl]-4,4′-dicarboxaldehyde
CAS：1809402-50-3

结构信息

单位分子式	C44H32CoN8.C14H10O2	单位分子量	941.94
配位金属	Co	配体	1) [1,1'-Biphenyl]-4,4'-dicarbaldehyde(CAS:66-98-8) 2) 5,10,15,20-tetrakis-(4-aminophenyl)-porphyrin-co-(ii)(CAS:67201-98-3)
孔径	~12 Å	孔容	0.2 cm³/g
比表面	442 m²/g
模拟结构

产品性状

产品形貌	紫色粉末，具有规则的矩形棒状形态 Purple Powders with Rectangular Rod-shaped Morphology
粒径	约100 nm

稳定性

1) COF-367-Co在水和乙醇中稳定
2) 热分解温度大于300℃

保存和活化方法

1) 常温或低温条件下，干燥密封保存
2) 建议使用前室温真空烘箱活化3小时

其他特性

荧光: 未提及

应用领域

1) 光催化CO2还原生成CO，具有高选择性和活性
2) 可用于可见光驱动的光催化反应

表征图谱

XRD

SEM

BET

FTIR

参考文献

1) Gong, Yun-Nan; Zhong, Wenhui; Li, Yang; Qiu, Yunze; Zheng, Lirong; Jiang, Jun; Jiang, Hai-Long; J. Am. Chem. Soc. 2020, 142, 16723−16731, DOI: 10.1021/jacs.0c07206; Regulating Photocatalysis by Spin-State Manipulation of Cobalt in Covalent Organic Frameworks【文献解读】

2) Liu, Wenbo; Li, Xiaokang; Wang, Chiming; Pan, Houhe; Liu, Wenping; Wang, Kang; Zeng, Qingdao; Wang, Rongming; Jiang, Jianzhuang; J. Am. Chem. Soc. 2019, 141, 17431−17440, DOI: 10.1021/jacs.9b09502; A Scalable General Synthetic Approach toward Ultrathin Imine-Linked Two-Dimensional Covalent Organic Framework Nanosheets for Photocatalytic CO2 Reduction

Cobalt, [[4,4′,4′′,4′′′-(21H,23H-porphine-5,10,15,20-tetrayl-κN21,κN22,κN23,κN24)tetrakis[benzenaminato]](2-)]-, (SP-4-1)-, polymer with [1,1′-biphenyl]-4,4′-dicarboxaldehyde

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