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1':3',1''-Terphenyl]-4, 4''- diamine, 5'-[4-amino-3, ethylethyl

4-[3,5-Bis[4-amino-3,5-di(propan-2-yl)phenyl]phenyl]-2,6-di(propan-2-yl)aniline

CAS NO.:1800490-20-3分子式:C42H57N3分子量:603.922091245651
产品名称:1,​3,​5-​tris(4'-​amino-​3',​5'-​isopropylphenyl)​benzene
其他名称:iPrTAPB;5'-​[4-​Amino-​3,​5-​bis(1-​methylethyl)​phenyl]​-​3,​3'',​5,​5''-​tetrakis(1-​methylethyl)​[1,​1':3',​1''-​terphenyl]​-​4,​4''-​diamine
CAS:1800490-20-3
结构信息
分子式 C42H57N3 分子量 603.92208
性状照片  
性质说明
1) 可溶于DCM、DMF、DMSO等
2) 2-8℃密封保存
合成应用
1) 可作为单体用于合成COF材料:iPrTAPB-​TFP, iPrTAPB-​TFPB [r1]; iPrTAPB-​Azo-​COP [r2]; 3D-HOF [r3, r4, r5]
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1)Kaleeswaran, D.; Vishnoi, Pratap; Murugavel, Ramaswamy; J. Mater. Chem. C 2015, 3(27), 7159-7171, DOI: 10.1039/C5TC00670H ; [3+3] Imine and β-​ketoenamine tethered fluorescent covalent-​organic frameworks for CO2 uptake and nitroaromatic sensing
2)Kaleeswaran, Dhananjayan; Murugavel, Ramaswamy; J. Chem. Sci. 2018, 130(1), 1-14, DOI: 10.1007/s12039-017-1403-2 ; Picric acid sensing and CO2 capture by a sterically encumbered azo-​linked fluorescent triphenylbenzene based covalent organic polymer
3) Wu, Xiaowei; Han, Xing; Liu, Yuhao; Liu, Yan; Cui, Yong; Journal of the American Chemical Society 2018, 140(47), 16124-16133, DOI: 10.1021/jacs.8b08452 ; Control Interlayer Stacking and Chemical Stability of Two-​Dimensional Covalent Organic Frameworks via Steric Tuning
4) Wu, Xiaowei; Han, Xing; Xu, Qisong; Liu, Yuhao; Yuan, Chen; Yang, Shi; Liu, Yan; Jiang, Jianwen; Cui, Yong; Journal of the American Chemical Society 2019, 141(17), 7081-7089, DOI:10.1021/jacs.9b02153 ; Chiral BINOL-​Based Covalent Organic Frameworks for Enantioselective Sensing

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