产品名称:1,3,5-tris(4'-amino-3',5'-isopropylphenyl)benzene
其他名称:iPrTAPB;5'-[4-Amino-3,5-bis(1-methylethyl)phenyl]-3,3'',5,5''-tetrakis(1-methylethyl)[1,1':3',1''-terphenyl]-4,4''-diamine
CAS:1800490-20-3
3) Wu, Xiaowei; Han, Xing; Liu, Yuhao; Liu, Yan; Cui, Yong; Journal of the American Chemical Society 2018, 140(47), 16124-16133, DOI: 10.1021/jacs.8b08452 ; Control Interlayer Stacking and Chemical Stability of Two-Dimensional Covalent Organic Frameworks via Steric Tuning
4) Wu, Xiaowei; Han, Xing; Xu, Qisong; Liu, Yuhao; Yuan, Chen; Yang, Shi; Liu, Yan; Jiang, Jianwen; Cui, Yong; Journal of the American Chemical Society 2019, 141(17), 7081-7089, DOI:10.1021/jacs.9b02153 ; Chiral BINOL-Based Covalent Organic Frameworks for Enantioselective Sensing
其他名称:iPrTAPB;5'-[4-Amino-3,5-bis(1-methylethyl)phenyl]-3,3'',5,5''-tetrakis(1-methylethyl)[1,1':3',1''-terphenyl]-4,4''-diamine
CAS:1800490-20-3
结构信息
分子式 | C42H57N3 | 分子量 | 603.92208 | ||
性状照片 |
性质说明
1) 可溶于DCM、DMF、DMSO等
2) 2-8℃密封保存
2) 2-8℃密封保存
合成应用
1) 可作为单体用于合成COF材料:iPrTAPB-TFP, iPrTAPB-TFPB [r1]; iPrTAPB-Azo-COP [r2]; 3D-HOF [r3, r4, r5]
表征图谱
参考文献
1)Kaleeswaran, D.; Vishnoi, Pratap; Murugavel, Ramaswamy; J. Mater. Chem. C 2015, 3(27), 7159-7171, DOI: 10.1039/C5TC00670H ; [3+3] Imine and β-ketoenamine tethered fluorescent covalent-organic frameworks for CO2 uptake and nitroaromatic sensing
2)Kaleeswaran, Dhananjayan; Murugavel, Ramaswamy; J. Chem. Sci. 2018, 130(1), 1-14, DOI: 10.1007/s12039-017-1403-2 ; Picric acid sensing and CO2 capture by a sterically encumbered azo-linked fluorescent triphenylbenzene based covalent organic polymer