产品名称：3,4-Dimethylthieno[2,3-b]thiophene-2,5-dicarboxylic acid
其他名称：H2DMTDC
CAS：175202-55-8
其他名称：H2DMTDC
CAS：175202-55-8
结构信息
| 分子式 | C10H8O4S2 | 分子量 | 256.29812 | ||
| 性状照片 | |||||
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料：IFMC-27 / IFMC-28 [r1] ; Zr(DMTDC)[r2] ; NENU‐512 [r3] ; Ln(DMTDC)1.5(H2O)2 (Ln = Eu , Tb , Gd , Dy , Er) [r5]; UIO-66(Ce)-DMTDC [r6]
表征图谱
参考文献
1) Yang, G.; Lang, Z.; Zang, H.; Lan, Y.; He, W.; Zhao, X.; Yan, L.; Wang, X.; Su, Z.; Chem. Commun. 2013, 49(11), 1088-1090, DOI: 10.1039/c2cc36894c ;
Control of interpenetration in S-containing metal–organic frameworks for selective separation of transition metal ions
2) Wang, K.; Huang, H.; Xue, W.; Liu, D.; Zhao, X.; Xiao, Y.; Li, Z.; Yang, Q.; Wang, L.; Zhong, C.; CrystEngComm 2015, 17(19), 3586-3590, DOI: 10.1039/C5CE00269A ; An ultrastable Zr metal-organic framework with a thiophene-type ligand containing methyl groups
3) He, W.; Yang, G.; Tang, Y.; Li, S.; Zhang, S.; Su, Z.; Lan, Y.; Chem.- Eur. J. 2015, 21(27), 9784-9789, DOI: 10.1002/chem.201500815 ; Phenyl Groups Result in the Highest Benzene Storage and Most Efficient Desulfurization in a Series of Isostructural Metal-Organic Frameworks
4) Qin, J.; Du, D.; Li, M.; Lian, X.; Dong, L.; Bosch, M.; Su, Z.; Zhang, Q.; Li, S.; Lan, Y.; Yuan, S.; Zhou, H.; J. Am. Chem. Soc. 2016, 138, 16, 5299-5307, DOI: 10.1021/jacs.6b01093 ; 10.1021/jacs.6b01093 ; Derivation and Decoration of Nets with Trigonal-Prismatic Nodes: A Unique Route to Reticular Synthesis of Metal-Organic Frameworks5) Wang, S.; Cao, T.; Yan, H.; Li, Y.; Lu, J.; Ma, R.; Li, D.; Dou, J.; Bai, J.; Inorg. Chem. 2016, 55(11), 5139-5151, DOI: 10.1021/acs.inorgchem.5b02801 ; Functionalization of Microporous Lanthanide-Based Metal-Organic Frameworks by Dicarboxylate Ligands with Methyl-Substituted Thieno[2,3-b]thiophene Groups: Sensing Activities and Magnetic Properties6) Dalapati, R.; Sakthivel, B.; Ghosalya, M.; Dhakshinamoorthy, A.; Biswas, S.; CrystEngComm 2017, 19(39), 5915-5925, DOI: 10.1039/C7CE01053B ; A cerium-based metal-organic framework having inherent oxidase-like activity applicable for colorimetric sensing of biothiols and aerobic oxidation of thiols
