产品名称：1,1'-(Benzene-1,4-Diyldimethylene)-Bis(3,5-Dimethyl-1H-Pyrazole)
其他名称：1,1'-(苯-1,4-二基二甲基)-双(3,5-二甲基-1H-吡唑)；bdb；1,4-bis((3,5-dimethyl-1H-pyrazol-1-yl)methyl)benzene
CAS：172606-22-3
其他名称：1,1'-(苯-1,4-二基二甲基)-双(3,5-二甲基-1H-吡唑)；bdb；1,4-bis((3,5-dimethyl-1H-pyrazol-1-yl)methyl)benzene
CAS：172606-22-3
结构信息
| 分子式 | C18H22N4 | 分子量 | 294.39408 | ||
| 性状照片 | |||||
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料：[Ag(μ-bpb)2] [r4]; [Cu(μ-bpb)2](PF6) [r5]
表征图谱
参考文献
1) Hartshorn, Chris M.; Steel, Peter J.; Australian J. Chem. 1995, 48(9), 1587-1599, DOI: 10.1071/CH9951587 ; Poly(pyrazol-1-ylmethyl)benzenes: new multidentate ligands
2) Wang, Xin-Yu; Liu, Shu-Qing; Zhang, Chun-Yan; Song, Ge; Bai, Feng-Ying; Xing, Yong-Heng; Shi, Zhan; Polyhedron 2012, 47(1), 151-164, DOI: 10.1016/j.poly.2012.08.016 ; Synthesis, structural, and biological evaluation of the arene-linked pyrazolyl methane ligands and their d9/d10 metal complexes
3) Budhai, Asheena; Omondi, Bernard; Ojwach, Stephen O.; Obuah, Collins; Osei-Twum, Emmanuel Y.; Darkwa, James; Catalysis Sci. Tech. 2013, 3(12), 3130-3135, DOI: 10.1039/c3cy00334e ; Tandem ethylene oligomerisation and Friedel-Crafts alkylation of toluene catalysed by bis-(3,5-dimethylpyrazol-1-ylmethyl)benzene nickel(ii) complexes and ethylaluminium dichloride
4) Azizzadeh, Sara; Nobakht, Valiollah; Carlucci, Lucia; Proserpio, Davide M.; Polyhedron 2017, 130, 58-66, DOI: 10.1016/j.poly.2017.03.048 ; Self-assembly of three cationic silver(I) coordination networks with flexible bis(pyrazolyl)-based linkers
5) Baladi, Elham; Nobakht, Valiollah; Tarassoli, Abbas; Proserpio, Davide M.; Carlucci, Lucia; Cryst. Growth & Des. 2018, 18(11), 7207-7218, DOI: 10.1021/acs.cgd.8b01446 ; Three Cationic, Nonporous CuI-Coordination Polymers: Structural Investigation and Vapor Iodine Capture
