产品名称:4'-[1,2,2-tris(4'-carboxy[1,1'-biphenyl]-4-yl)ethenyl]- [1,1'-Biphenyl]-4-carboxylic acid
其他名称:四[4-(4'-羧基苯基)苯基]乙烯;H4ETTC; H4TCPE
CAS: 1610858-96-2
其他名称:四[4-(4'-羧基苯基)苯基]乙烯;H4ETTC; H4TCPE
CAS: 1610858-96-2
结构信息
分子式 | C54H36O8 | 分子量 | 812.85884 | ||
性状照片 |
性质说明
1) 1610858-96-2 溶于DMF、DMSO等
2) 室温密封保存
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:PCN-94 [r1]; PCN-128 [r2, r4]; LMOF-231 [r3]; Zr/Hf TCPE [r5]
表征图谱
参考文献
1) Wei, Z.; Gu, Z.-Y.; Arvapally, R. K.; Chen, Y.-P.; McDougald, R. N., Jr.; Ivy, J. F.; Yakovenko, A. A.; Feng, D.; Omary, M. A.; Zhou, H.-C. J. Am. Chem. Soc. 2014, 136, 8269-8276, DOI:10.1021/ja5006866 ; Rigidifying Fluorescent Linkers by Metal–Organic Framework Formation for Fluorescence Blue Shift and Quantum Yield Enhancement
2) Zhang, Q.; Su, J.; Feng, D.; Wei, Z.; Zou, X.; Zhou, H.-C.; J. Am. Chem. Soc. 2015, 137, 10064-10067, DOI:10.1021/jacs.5b04695 ; Piezofluorochromic Metal–Organic Framework: A Microscissor Lift
3) Lustig, W.; Wang, F.; Teat, S.; Hu, Z.; Gong, Q.; Li, J.; Inorg. Chem. 2016, 55, 15, 7250-7256 DOI: 10.1021/acs.inorgchem.6b00897 ; Chromophore-Based Luminescent Metal–Organic Frameworks as Lighting Phosphors
4) Li, P.; Moon, S.; Guelta, M.; Harvey, S.; Hupp, J.; Farha, O.; J. Am. Chem. Soc. 2016, 138(26), 8052-8055, DOI:10.1021/jacs.6b03673 ; Encapsulation of a Nerve Agent Detoxifying Enzyme by a Mesoporous Zirconium Metal–Organic Framework Engenders Thermal and Long-Term Stability