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四[4-(4'-羧基苯基)苯基]乙烯

4',4'',4''',4''''-(ethene-1,1,2,2-tetrayl)tetrabiphenyl-4-carboxylic acid

CAS NO.:1610858-96-2分子式:C54H36O8分子量:812.85884
产品名称:4'-​[1,​2,​2-​tris(4'-​carboxy[1,​1'-​biphenyl]​-​4-​yl)​ethenyl]​- [1,​1'-​Biphenyl]​-​4-​carboxylic acid
其他名称:四[4-(4'-羧基苯基)苯基]乙烯;H4ETTC; H4TCPE
CAS: 1610858-96-2
结构信息
分子式  C54H36O8 分子量  812.85884
性状照片
性质说明
1) 1610858-96-2 溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:PCN-94 [r1]; PCN-128 [r2, r4]; LMOF-231 [r3]; Zr/Hf TCPE [r5]
表征图谱
HNMR
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Wei, Z.; Gu, Z.-Y.; Arvapally, R. K.; Chen, Y.-P.; McDougald, R. N., Jr.; Ivy, J. F.; Yakovenko, A. A.; Feng, D.; Omary, M. A.; Zhou, H.-C.  J. Am. Chem. Soc. 2014, 136, 8269-8276, DOI:10.1021/ja5006866 ; Rigidifying Fluorescent Linkers by Metal–Organic Framework Formation for Fluorescence Blue Shift and Quantum Yield Enhancement 
2) Zhang, Q.; Su, J.; Feng, D.; Wei, Z.; Zou, X.; Zhou, H.-C.; J. Am. Chem. Soc. 2015, 137, 10064-10067, DOI:10.1021/jacs.5b04695 ; Piezofluorochromic Metal–Organic Framework: A Microscissor Lift 
3) Lustig, W.; Wang, F.; Teat, S.; Hu, Z.; Gong, Q.; Li, J.; Inorg. Chem. 2016, 55, 15, 7250-7256 DOI: 10.1021/acs.inorgchem.6b00897 ; Chromophore-Based Luminescent Metal–Organic Frameworks as Lighting Phosphors 
4) Li, P.; Moon, S.; Guelta, M.; Harvey, S.; Hupp, J.; Farha, O.;  J. Am. Chem. Soc. 2016, 138(26), 8052-8055, DOI:10.1021/jacs.6b03673 ; Encapsulation of a Nerve Agent Detoxifying Enzyme by a Mesoporous Zirconium Metal–Organic Framework Engenders Thermal and Long-Term Stability
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