材料名称：DhaTp
其他名称：2,5-DhaTph ; H2P-DHPh COF ; H2P-DHPhx COF
CAS：1529776-43-9
其他名称：2,5-DhaTph ; H2P-DHPh COF ; H2P-DHPhx COF
CAS：1529776-43-9
结构信息
| 单位分子式 | C52H40N8O4 | 单位分子量 | 840.94 | ||
| 单体 |
2,5-dihydroxy-1,4-Benzenedicarboxaldehyde (CAS: 1951-36-6); 5,10,15,20-Tetrakis(4-Aminophenyl)-21H,23H-Porphine (CAS: 22112-84-1) |
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| 孔径 | 2 nm | 孔容 | 0.8 cm3/g | ||
| 比表面 | BET比表面>900m2 | ||||
| 模拟结构 |   |
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产品性状
| 产品形貌 |
深紫色粉末
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| 粒径 | 不规则团聚体 | |||
稳定性
1) DhaTp在水溶液和酸洗溶液中稳定数日
保存和活化方法
1) 常温或低温条件下，干燥密封保存
其他特性
荧光:NA
应用领域
1) 用于气体和污染物吸附
2) 良好的孔道可用于负载其他催化剂
2) 良好的孔道可用于负载其他催化剂
3) 羟基可用于配位吸附其他金属或进一步衍生接肢
表征图谱
参考文献
1）Kandambeth, Sharath; Shinde, Digambar Balaji; Panda, Manas K.; Lukose, Binit; Heine, Thomas; Banerjee, Rahul; Angewandte Chemie, International Edition 2013, 52(49), 13052-13056, DOI: 10.1002/anie.201306775 ; Enhancement of Chemical Stability and Crystallinity in Porphyrin-Containing Covalent Organic Frameworks by Intramolecular Hydrogen Bonds【文献解读】；
2）Xu, Hong; Chen, Xiong; Gao, Jia; Lin, Jianbin; Addicoat, Matthew; Irle, Stephan; Jiang, Donglin; Chemical Communications 2014, 50(11), 1292-1294, DOI: 10.1039/c3cc48813f ; Catalytic covalent organic frameworks via pore surface engineering；
3）Huang, Ning; Chen, Xiong; Krishna, Rajamani; Jiang, Donglin; Angewandte Chemie, International Edition 2015, 54(10), 2986-2990, DOI: 10.1002/anie.201411262 ; Two-Dimensional Covalent Organic Frameworks for Carbon Dioxide Capture through Channel-Wall Functionalization；
4) Yonghang Yang, Baokun Liang, Jakob Kreie, Mike Hambsch, Zihao Liang,Cheng Wang, Senhe Huang, Xin Dong, Li Gong, Chaolun Liang, Dongyang Lou,Zhipeng Zhou, Jiaxing Lu, Yang Yang, Xiaodong Zhuang, Haoyuan Qi, Ute Kaiser,Stefan C. B. Mannsfeld, Wei Liu, Armin Gölzhäuser & Zhikun Zheng; Nature 630, 878–883, 2024; DOI：10.1038/s41586-024-07505-x; Elastic films of single-crystal two-dimensional covalent organic frameworks【文献解读】;
