产品名称:2,4,6-Trimethyl-1,3,5-benzenetrimethanamine
其他名称:(2,4,6-Trimethylbenzene-1,3,5-triyl)trimethanamine; 1,3,5-Triaminomethyl-2,4,6-trimethylbenzene; [3,5-Bis(aminomethyl)-2,4,6-trimethylphenyl]methanamine
CAS:149525-64-4
3) Arunachalam, M.; Ghosh, Pradyut; Chem. Commun. 2009, (36), 5389-5391, DOI: 10.1039/b910014h ; Recognition and complexation of hydrated fluoride anion: F2(H2O)62- templated formation of a dimeric capsule of a tripodal amide
其他名称:(2,4,6-Trimethylbenzene-1,3,5-triyl)trimethanamine; 1,3,5-Triaminomethyl-2,4,6-trimethylbenzene; [3,5-Bis(aminomethyl)-2,4,6-trimethylphenyl]methanamine
CAS:149525-64-4
结构信息
分子式 | C12H21N3 | 分子量 | 207.32 | ||
性状照片 |
性质说明
1) 可溶于DCM、DMF、DMSO等
2) 2-8℃密封保存
2) 2-8℃密封保存
合成应用
1) 可作为单体用于合成COF材料:
2) 可作为分子笼单体中间体: OCD1 (Tri4Di4Tet1)
表征图谱
参考文献
1) Stack, T. D. P.; Hou, Zhiguo; Raymond, Kenneth N.; Journal of the American Chemical Society 1993, 115(14), 6466-6467, DOI: 10.1021/ja00067a094 ; Rational reduction of the conformational space of a siderophore analog through nonbonded interactions: the role of entropy in enterobactin
2) Arunachalam, M.; Ravikumar, I.; Ghosh, Pradyut; J. Org. Chem. 2008, 73(22), 9144-9147, DOI: 10.1021/jo801762b ; A New Hexaaza Bicyclic Cyclophane with Dual Binding Sites4) Acharyya, Koushik; Mukherjee, Partha Sarathi; Chem. Commun., 2014,50, 15788-15791, DOI: 10.1039/C4CC06225F ; A fluorescent organic cage for picric acid detection
5) Greenaway, R. L.; Santolini, V.; Bennison, M. J.; Alston, B. M.; Pugh, C. J.; Little, M. A.; Miklitz, M.; Eden-Rump, E. G. B.; Clowes, R.; Shakil, A.; Cuthbertson, H. J.; Armstrong, H.; Briggs, M. E.; Jelfs, K. E.; Cooper, A. I.; Nat. Commun. 2018, 9(1), 1-11, DOI: 10.1038/s41467-018-05271-9 ; High-throughput discovery of organic cages and catenanes using computational screening fused with robotic synthesis6) Greenaway, Rebecca L.; Santolini, Valentina; Szczypinski, Filip T.; Bennison, Michael J.; Little, Marc A.; Marsh, Andrew; Jelfs, Kim E.; Cooper, Andrew I.; Chem.- Eur. J. 2020, 26(17), 3718-3722, DOI: 10.1002/chem.201905623 ; Organic Cage Dumbbells