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5,15-diphenyl-10,20-di(4-carboxyphenyl)porphine

Benzoic acid, 4,​4'-​(10,​20-​diphenyl-​21H,​23H-​porphine-​5,​15-​diyl)​bis-

CAS NO.:142168-26-1分子式:C46H30N4O4分子量:702.7548
产品名称:4,​4'-​(10,​20-​Diphenyl-​21H,​23H-​porphine-​5,​15-​diyl)​bis[benzoic acid]
其他名称:DiCPP-​opp;trans-​H4DCPP;5,​15-​bis(4-​carboxyphenyl)​-​10,​20-​diphenylporphyrin
CAS:142168-26-1
结构信息
分子式  C46H30N4O4 分子量  702.7548
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:porphyrin paddle-​wheel framework (PPF-​25)​ [r2]; Zn-SURMOF-2 [r3] ; 二维MOF膜: NAFS‐31 [r4]
表征图谱
HNMR
NA
MS
FTIR
NA
HPLC
NA
参考文献
1) Li, Yang; Cao, Lifeng; Tian, He; J. Org. Chem. 2006, 71(21), 8279-8282, DOI: 10.1021/jo061161+ ; Fluoride ion-​triggered dual fluorescence switch based on naphthalimides winged zinc porphyrin
2) Liu, Jinxuan; Zhou, Wencai; Liu, Jianxi; Howard, Ian; Kilibarda, Goran; Schlabach, Sabine; Coupry, Damien; Addicoat, Matthew; Yoneda, Satoru; Tsutsui, Yusuke; Sakurai, Tsuneaki; Seki, Shu; Wang, Zhengbang; Lindemann, Peter; Redel, Engelbert; Heine, Thomas; Woell, Christof; Angew. Chem. Int. Ed. 2015, 54(25), 7441-7445, DOI: 10.1002/anie.201501862 ; Photoinduced Charge-​Carrier Generation in Epitaxial MOF Thin Films: High Efficiency as a Result of an Indirect Electronic Band Gap?
3) Zhao, Xin; Yuan, Lin; Zhang, Zeng-qi; Wang, Yong-song; Yu, Qiong; Li, Jun; Inorg. Chem. 2016, 55(11), 5287-5296, DOI: 10.1021/acs.inorgchem.6b00274 ; Synthetic Methodology for the Fabrication of Porous Porphyrin Materials with Metal-​Organic-​Polymer Aerogels
142168-26-1-CS017616-NEG.pdf 下载

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