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4-[3,5-bis(2,6-dipyridin-2-ylpyridin-4-yl)phenyl]-2,6-dipyridin-2-ylpyridine

CAS NO.:142030-40-8分子式:C51H33N9分子量:771.86802
产品名称:1,​3,​5-​tris(2,​2':6',​2''-​terpyridyl)​benzene
其他名称:ttpb;4',​4'''',​4'''''''-​(1,​3,​5-​Benzenetriyl)​tris[2,​2':6',​2''-​terpyridine]
CAS:142030-40-8
结构信息
 
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:[Ru3(ttpb)​(L4E)​3]​(PF6)​6 [r3]
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Constable, Edwin C.; Thompson, Alexander M. W. Cargill; J. Chem. Soc., Dalton Trans. 1992, (24), 3467-3475, Multinucleating 2,​2':6',​2''-​terpyridine ligands as building blocks for the assembly of coordination polymers and oligomers
2) Newkome, George R.; Wang, Pingshan; Moorefield, Charles N.; Cho, Tae Joon; Mohapatra, Prabhu P.; Li, Sinan; Hwang, Seok-Ho; Lukoyanova, Olena; Echegoyen, Luis; Palagallo, Judith A.; Iancu, Violeta; Hla, Saw-Wai; Science 2006, 312(5781), 1782-1785, DOI: 10.1126/science.1125894 ; Nanoassembly of a Fractal Polymer: A Molecular "Sierpinski Hexagonal Gasket"
3) Terada, Keiichi; Kobayashi, Katsuaki; Haga, Masa-aki; Dalton Trans. 2008, (36), 4846-4854, DOI: 10.1039/b807526c ; Synthesis, electrochemical, and molecular inclusion properties of canopied' trinuclear ruthenium complexes with six anchoring groups on an ITO electrode
4) Winter, Andreas; Hoeppener, Stephanie; Newkome, George R.; Schubert, Ulrich S.; Adv. Mater. 2011, 23(31), 3484-3498, DOI: 10.1002/adma.201101251 ; Terpyridine-​Functionalized Surfaces: Redox-​Active, Switchable, and Electroactive Nanoarchitectures

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