材料名称:TpPa-1
其他名称:1,3,5-Benzenetricarboxaldehyde, 2,4,6-trihydroxy-, polymer with 1,4-benzenediamine
CAS:1414350-37-0
其他名称:1,3,5-Benzenetricarboxaldehyde, 2,4,6-trihydroxy-, polymer with 1,4-benzenediamine
CAS:1414350-37-0
结构信息
单位分子式 | C9H6O6.C6H8N2 | 单位分子量 | 318.28146 | ||
单体 | 1) 2,4,6-trihydroxy-1,3,5-benzenetricarbaldehyde (CAS:34374-88-4);
2) 1,4-benzenediamine (CAS:106-50-3) |
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孔径 | 1.8nm | 孔容 | 0.087 cm3/g | ||
比表面 | BET比表面520m2/g | ||||
模拟结构 |
产品性状
产品形貌 |
红色或深橙色粉末 Red or dark orange solid |
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粒径 |
稳定性
1) 水溶液和酸性环境下稳定,强碱性条件下不稳定
保存和活化方法
1) 常温或低温条件下,干燥密封保存
其他特性
荧光:NA
应用领域
1) 用于气体和污染物吸附
2) 良好的孔道可用于负载其他催化剂
2) 良好的孔道可用于负载其他催化剂
表征图谱
参考文献
1) S. Kandambeth, A. Mallick, B. Lukose, M.V. Mane, T. Heine, R. Banerjee, J. Am. Chem. Soc. 2012, 134, 19524-19527 ; DOI: 10.1021/ja308278w ; Construction of Crystalline 2D Covalent Organic Frameworks with Remarkable Chemical (Acid/Base) Stability via a Combined Reversible and Irreversible Route【文献解读】
2) Y. Peng, W.K. Wong, Z. Hu, Y. Cheng, D. Yuan, S. A. Khan, D. Zhao, Chem. Mater. 2016, 28, 14, 5095-5101, DOI: 10.1021/acs.chemmater.6b01954 ; Room Temperature Batch and Continuous Flow Synthesis of Water-Stable Covalent Organic Frameworks (COFs);
3) Anoop Singh, Narinder Singh,* and Navneet Kaur*; ACS Food Sci. Technol. 2024; DOI:10.1021/acsfoodscitech.4c00565; Design, Synthesis, and Antimicrobial Activity of Biodegradable Sodium Alginate/COF Polymeric Films for Smart Monitoring of Food Spoilage and Active Food Packaging;文献解读
4) Haijun Hu, Xiaodong Sun,* Hui Li, Hongge Pan, Yali Ma,* Hongwei Huang, and Tianyi Ma*; Small 2024, 2407117; DOI: 10.1002/smll.202407117; Construction of 2D/2D Pd Metallene/COFs System with Strong Internal Electric Field for Outstanding Solar Energy Photocatalysis【文献解读】
TpPa-1 CS018259-XRD.png | 下载 |