产品名称： Tetrathiafulvalene-3,4,5,6-tetrakis(4-benzoic acid)
其他名称： H4TTFTB; 四硫富瓦烯四苯甲酸
CAS： 1392413-73-8
其他名称： H4TTFTB; 四硫富瓦烯四苯甲酸
CAS： 1392413-73-8
结构信息
| 分子式 | C34H20O8S4 | 分子量 | 684.78 | ||
| 性状照片 | 棕色固体 | ||||
性质说明
1) 1392413-73-8 溶于DMF、DMSO等
2) 室温密封保存
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料：M2(TTFTB) M=Mn, Co, Zn, Cd [r1, r3]]; MIT-25 [r2]
2) 可用于合成HOF材料： X-TTF-1
表征图谱
参考文献
1) T. C. Narayan , T. Miyakai , S. Seki and M. Dincă , J. Am. Chem. Soc. 2012, 134 , 12932-12935, DOI:10.1021/ja3059827 ; High Charge Mobility in a Tetrathiafulvalene-Based Microporous Metal–Organic Framework
2) S. S. Park , C. H. Hendon , A. J. Fielding , A. Walsh , M. O'Keeffe and M. Dinca , J. Am. Chem. Soc. 2017, 139 , 3619-3622, DOI:10.1021/jacs.6b13176 ; The Organic Secondary Building Unit: Strong Intermolecular π Interactions Define Topology in MIT-25, a Mesoporous MOF with Proton-Replete Channels
3) Park, S.; Hontz, E.; Sun, L.; Hendon, C.; Walsh, A.; Van Voorhis, T.; Dinca, M.; J. Am. Chem. Soc. 2015, 137(5), 1774-1777, DOI:10.1021/ja512437u ; Cation-Dependent Intrinsic Electrical Conductivity in Isostructural Tetrathiafulvalene-Based Microporous Metal–Organic Frameworks
4) Chen, B.; Lv, Z.; Leong, C.; Zhao, Y.; D'Alessandro, D.; Zuo, J.; Cryst. Growth. Des. 2015, 15(4), 1861-1870, DOI: 10.1021/acs.cgd.5b00014 ; Crystal Structures, Gas Adsorption, and Electrochemical Properties of Electroactive Coordination Polymers Based on the Tetrathiafulvalene-Tetrabenzoate Ligand
