产品名称：(biphenyl-3, 3′,5, 5′-tetra-(phenyl-4-carboxylic acid))
其他名称：H4TCBP
CAS：1383925-31-2
其他名称：H4TCBP
CAS：1383925-31-2
结构信息
| 分子式 | C40H26O8 | 分子量 | 634.62964 | ||
| 性状照片 |  |
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性质说明
1) 1383925-31-2 可溶于DMF、DMSO等
2) 室温密封保存
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料: NOTT-202 [r1]; ZJU-30 [r2]; HOF-TCBP [r3]; NU-1010 [r4]; UMCM-312/UMCM-313 [r5]
2) 可作为单体合成HOF材料: HOF-TCBP [r3]
表征图谱
参考文献
1) Yang, S.; Lin, X.; Lewis, W.; Suyetin, M.; Bichoutskaia, E.; Parker, J.; Tang, C.; Allan, D.; Rizkallah, P.; Hubberstey, P.; Champness, N.; Thomas, K.; Blake, A.; Schröder, M. Nat. Mater. 2012, 11, 710–716, DOI: 10.1038/nmat3343 ; A partially interpenetrated metal–organic framework for selective hysteretic sorption of carbon dioxide
2) Cai, J.; Yu, J.; Xu, H.; He, Y.; Duan, X.; Cui, Y.; Wu, C.; Chen, B.; Qian, G. Cryst. Growth Des. 2013, 13, 5, 2094-2097, DOI: 10.1021/cg400164m ; A Doubly Interpenetrated Metal–Organic Framework with Open Metal Sites and Suitable Pore Sizes for Highly Selective Separation of Small Hydrocarbons at Room Temperature
3) Hu, F.; Liu, C.; Wu, M.; Pang, J.; Jiang, F.; Yuan, D.; Hong, M. Angew. Chem., Int. Ed. 2017, 56(8), 2101-2104, DOI:10.1002/anie.201610901 ; An Ultrastable and Easily Regenerated Hydrogen‐Bonded Organic Molecular Framework with Permanent Porosity
4) Kato, S.; Otake, K.-i.; Chen, H.; Akpinar, I.; Buru, C. T.; Islamoglu, T.; Snurr, R. Q.; Farha, O. K. J. Am. Chem. Soc. 2019, 141, 2568– 2576, DOI: 10.1021/jacs.8b12525 ; Zirconium-Based Metal–Organic Frameworks for the Removal of Protein-Bound Uremic Toxin from Human Serum Albumin
5) Ma, J.; Tran, L.; Matzger, A.; Cryst. Growth Des. 2016, 16(7), 4148-4153, DOI:10.1021/acs.cgd.6b00698 ; Toward Topology Prediction in Zr-Based Microporous Coordination Polymers: The Role of Linker Geometry and Flexibility
