产品名称: 2,5-Dichloroterephthalic acid
其他名称: 2,5-二氯对苯二甲酸; BDC-Cl2
CAS:13799-90-1
其他名称: 2,5-二氯对苯二甲酸; BDC-Cl2
CAS:13799-90-1
结构信息
分子式 | C8H4O4Cl2 | 分子量 | 235.02096 | ||
性状照片 |
性质说明
1) 13799-90-1 溶于DMF、DMSO等
2) 室温密封保存
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料: MOF-5-Cl2 [r1]; [Zn2(bdc-Cl2)2(dabco)] [r4] ; UIO-66-Cl2 [r5]
表征图谱
参考文献
1) Deng, Hexiang; Doonan, Christian J.; Furukawa, Hiroyasu; Ferreira, Ricardo B.; Towne, John; Knobler, Carolyn B.; Wang, Bo; Yaghi, Omar M.; Science 2010, 327(5967), 846-850, DOI: 10.1126/science.1181761 ; Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks
2) Uemura, Takashi; Ono, Yukari; Hijikata, Yuh; Kitagawa, Susumu; J. Am. Chem. Soc. 2010, 132(13), 4917-4924, DOI: 10.1021/ja100406k ; Functionalization of Coordination Nanochannels for Controlling Tacticity in Radical Vinyl Polymerization
3) Xue, Ming; Zhang, Zhangjing; Xiang, Shengchang; Jin, Zhao; Liang, Chengdu; Zhu, Guang-Shan; Qiu, Shi-Lun; Chen, Banglin; J. Mater. Chem. 2010, 20(19), 3984-3988, DOI: 10.1039/b927486c ; Selective gas adsorption within a five-connected porous metal-organic framework
4) Uemura, Kazuhiro; Yamasaki, Yukari; Onishi, Fumiaki; Kita, Hidetoshi; Ebihara, Masahiro; Inorg. Chem. 2010, 49(21), 10133-10143, DOI: 10.1021/ic101517t ; Two-Step Adsorption on Jungle-Gym-Type Porous Coordination Polymers: Dependence on Hydrogen-Bonding Capability of Adsorbates, Ligand-Substituent Effect, and Temperature
5) Biswas, Shyam; Van Der Voort, Pascal; Eur. J. Inorg. Chem. 2013, 2013(12), 2154-2160, DOI: 10.1002/ejic.201201228 ; A General Strategy for the Synthesis of Functionalised UiO-66 Frameworks: Characterisation, Stability and CO2 Adsorption Properties