产品名称:1,3-Di(2-pyridyl)benzene
其他名称:DPBH;2,2'-(1,3-Phenylene)bis[pyridine]; 1,3-Bis(2-pyridinyl)benzene; 1,3-Bis(2-pyridyl)benzene;
CAS:136538-84-6
3) Williams, J. A. Gareth; Beeby, Andrew; Davies, E. Stephen; Weinstein, Julia A.; Wilson, Claire; Inorg. Chem. 2003, 42(26), 8609-8611, DOI: 10.1021/ic035083+ ; An Alternative Route to Highly Luminescent Platinum(II) Complexes: Cyclometalation with N-C-N-Coordinating Dipyridylbenzene Ligands
4) Soro, Barbara; Stoccoro, Sergio; Minghetti, Giovanni; Zucca, Antonio; Cinellu, Maria Agostina; Gladiali, Serafino; Manassero, Mario; Sansoni, Mirella; Organometallics 2005, 24(1), 53-61, DOI: 10.1021/om040102o ; Synthesis of the First C-2 Cyclopalladated Derivatives of 1,3-Bis(2-pyridyl)benzene. Crystal Structures of [Hg(N-C-N)Cl], [Pd(N-C-N)Cl], and [Pd2(N-C-N)2(μ-OAc)]2[Hg2Cl6]. Catalytic Activity in the Heck Reaction
其他名称:DPBH;2,2'-(1,3-Phenylene)bis[pyridine]; 1,3-Bis(2-pyridinyl)benzene; 1,3-Bis(2-pyridyl)benzene;
CAS:136538-84-6
结构信息
分子式 | C16H12N2 | 分子量 | 232.27988 | ||
性状照片 |
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:Ru(tterpy)(dpb) [r1]
表征图谱
参考文献
1) Beley, Marc; Collin, Jean Paul; Louis, Remy; Metz, Bernard; Sauvage, Jean Pierre; J. Am. Chem. Soc. 1991, 113(22), 8521-8522, DOI: 10.1021/ja00022a049 ; 3,3',5,5'-Tetrapyridylbiphenyl, a bis-cyclometalating bridging ligand with a high coupling ability in ruthenium(III), ruthenium(II) mixed valence systems
2) Cardenas, Diego J.; Echavarren, Antonio M.; Ramirez de Arellano, M. Carmen; Organometallics 1999, 18(17), 3337-3341, DOI: 10.1021/om990125g ; Divergent Behavior of Palladium(II) and Platinum(II) in the Metalation of 1,3-Di(2-pyridyl)benzene5) Kletsch, Lukas; Hoerner, Gerald; Klein, Axel; Organometallics 2020, 39(15), 2820-2829, DOI: 10.1021/acs.organomet.0c00355 ; Cyclometalated Ni(II) Complexes [Ni(N[symbol omitted]C[symbol omitted]N)X] of the Tridentate 2,6-di(2-pyridyl)phenide Ligand