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4,4′-[1,4-Phenylenebis(oxy)]bis[benzoic acid]

CAS NO.:13282-09-2分子式:C20H14O6分子量:350.32156
产品名称:4,​4'-​(1,​4-​Phenylenedioxy)​dibenzoic acid
其他名称:H2PBDC;4,​4'-​[1,​4-​Phenylenebis(oxy)​]​bis[benzoic acid]​; 1,​4-​Bis(4-​carboxyphenoxy)​benzene; 1,​4-​bis(4-​phenoxy)​benzenedicarboxylic acid
CAS:13282-09-2
结构信息
分子式 C20H14O6 分子量 350.32156
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:PET; Polyimide ; [Zn3(PBDC)​3(4,​4'-​bipy)​]​ [r4]
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Evers, Robert C.; Arnold, Fred E.; Helminiak, Thaddeus E.; Macromolecules 1981, 14(4), 925-930, DOI: 10.1021/ma50005a007 ; Articulated all-​para polymers with 2,​6-​benzobisoxazole, 2,​6-​benzobisthiazole, and 2,​6-​benzobisimidazole units in the backbone
2) Eastmond, G. C.; Paprotny, J.; Irwin, R. S.; Polymer 1998, 1999, 40(2), 469-486, DOI: 10.1016/S0032-3861(98)00228-6 ; 1,​2-​Bis(carboxyphenoxy)​arylenes and aramids and polyarylates therefrom: synthesis and properties
3) Zhao, Jing; Xu, Hongjie; Fang, Jianhua; Yin, Jie; J. Appl. Polym. Sci. 2012, 126(1), 244-252, DOI: 10.1002/app.36979 ; Synthesis and characterization of novel aromatic polyamides via Yamazaki-​Higashi phosphorylation method
4) Hong, Jianquan; Huo, Lianguang; Wang, Yazhao; Long, Ruixue; Zheng, Changge; Inorganica Chimica Acta 2017, 455, 81-87, DOI: 10.1016/j.ica.2016.10.016 ; Syntheses, crystal structures and properties of two coordination polymers derived from flexible dicarboxylate and N-​donor ligands

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