材料名称：TPB-TP-COF
其他名称：TAPB-TA COF;SCOF-IC1；TAPB-TPA COF ;1,4-Benzenedicarboxaldehyde, polymer with 5′-(4-aminophenyl)[1,1′:3′,1′′-terphenyl]-4,4′′-diamine
CAS：1262433-88-4
其他名称：TAPB-TA COF;SCOF-IC1；TAPB-TPA COF ;1,4-Benzenedicarboxaldehyde, polymer with 5′-(4-aminophenyl)[1,1′:3′,1′′-terphenyl]-4,4′′-diamine
CAS：1262433-88-4
结构信息
| 单位分子式 | C24H21N3.C8H6O2 | 单位分子量 | |||
| 单体 | 1) 1,3,5-三(4-氨基苯基)苯 TPB (CAS: 118727-34-7);
2) 对苯二甲醛 Terephthalaldehyde (CAS: 623-27-8) |
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| 孔径 | 3.4 nm | 孔容 | |||
| 比表面 | BET比表面 >500 m2/g | ||||
| 模拟结构 |  |
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产品性状
| 产品形貌 |
橙黄色粉末 Orange/Yellow powders |
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| 粒径 | 不规则团聚形貌 | |||
稳定性
1) TPB-TP COF 具有良好的稳定性, 在空气中可稳定数周。
2) 热分解温度大于300度
保存和活化方法
1) 常温或低温条件下，干燥密封保存
其他特性
荧光:NA
应用领域
1)用于气体和污染物吸附
2)良好的孔道可用于负载其他催化剂
2)良好的孔道可用于负载其他催化剂
表征图谱
参考文献
1) X.-H. Liu, C.-Z. Guan, S.-Y. Ding, W. Wang, H.-J. Yan, D. Wang, L.-J. Wan, J. Am. Chem. Soc. 2013, 135, 10470-10474, DOI: 10.1021/ja403464h ; On-Surface Synthesis of Single-Layered Two-Dimensional Covalent Organic Frameworks via Solid–Vapor Interface Reactions
2) P. J. Waller, S. J. Lyle, T. M. O. Popp, C. S. Diercks, J. A. Reimer, O. M. Yaghi, J. Am. Chem. Soc. 2016, 138, 15519-15522, DOI: 10.1021/jacs.6b08377 ; Chemical Conversion of Linkages in Covalent Organic Frameworks
3) H. Xu, J. Gao, D. Jiang, Nat. Chem. 2015, 7, 905-912, DOI: 10.1038/nchem.2352 ; Stable, crystalline, porous, covalent organic frameworks as a platform for chiral organocatalysts
4) B. J. Smith, A. C. Overholts, N. Hwang, W. R. Dichtel, Chem. Commun. 2016, 52, 3690-3693, DOI: 10.1039/C5CC10221A ; Insight into the crystallization of amorphous imine-linked polymer networks to 2D covalent organic frameworks
5) G. Lin, C. Gao, Q. Zheng, Z. Lei, H. Geng, Z. Lin, H. Yang, Z. Cai, Chem. Commun. 2017, 53, 3649-3652, DOI: 10.1039/C7CC00482F ; Room-temperature synthesis of core–shell structured magnetic covalent organic frameworks for efficient enrichment of peptides and simultaneous exclusion of proteins
6) M. Matsumoto, R. R. Dasari, W. Ji, C. H. Feriante, T. C. Parker, S. R. Marder, W. R. Dichtel, J. Am. Chem. Soc. 2017, 139, 4999-5002, DOI: 10.1021/jacs.7b01240 ; Rapid, Low Temperature Formation of Imine-Linked Covalent Organic Frameworks Catalyzed by Metal Triflates；
7）Xuan-He Liu, Cui-Zhong Guan, San-Yuan Ding, Wei Wang, Hui-Juan Yan, Dong Wang*, and Li-Jun Wan*; J. Am. Chem. Soc. 2013, 135, 28, 10470–10474; DOI：10.1021/ja403464h; On-Surface Synthesis of Single-Layered Two-Dimensional Covalent Organic Frameworks via Solid−Vapor Interface Reactions【文献解读】;
8) Cheng Qian,* Anyang Qiu, Qihang Huang, Jiatong Liu, Qiang Gao, Hongwei Wu, and Yaozu Liao*; ACS Appl. Nano Mater. 2024, 7, 8, 9668–9677; DOI：10.1021/acsanm.4c01275; Dynamic Imine Exchange Enables Access to Nanoporous Covalent Organic Frameworks with High Crystallinity for the Heck Reaction【文献解读】;
9) Tianwei Xue, Olga A. Syzgantseva, Li Peng,* Ruiqing Li, Yuyu Guo, Chengbin Liu, Tongxin Qiao, Wenli Hao, Jiaran Li, Lilin Zhu, Shuliang Yang,* Jun Li,* and Wendy L. Queen*; J. Am. Chem. Soc. 2024; DOI：10.1021/jacs.4c10273; Preserving High Porosity of Covalent Organic Frameworks via Functional Polymer Guest Introduction【文献解读】
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