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四(4-咪唑苯基)甲烷

Tetrakis[4-(1-imidazolyl)phenyl]methane

CAS NO.:1258859-29-8分子式:C37H28N8分子量:584.67182
产品名称:tetrakis[4-​(1-​imidazolyl)​phenyl]​methane
其他名称:TIPM;1,​1',​1'',​1'''-​(Methanetetrayltetra​-​4,​1-​phenylene)​tetrakis[1H-​imidazole]
CAS:1258859-29-8
结构信息
分子式  C37H28N8 分子量  584.67182
性状照片  
性质说明
1)1258859-29-8  可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:SCU-100[r2];  SCU-101[r3]
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Choi, J.; Yang, Y.; Kim, H.; Son, S.; Angew. Chem., Int. Ed. 2010, 49(42), 7718-7722, DOI:10.1002/anie.201003101 ; Organometallic Hollow Spheres Bearing Bis(N‐Heterocyclic Carbene)–Palladium Species: Catalytic Application in Three‐Component Strecker Reactions   
2) Sheng, D.; Zhu, L.; Xu, C.; Xiao, C.; Wang, Y.; Wang, Y.; Chen, L.; Diwu, J.; Chen, J.; Chai, Z.; Albrecht-Schmitt, T. E.; Wang, S. Environ. Sci. Technol. 2017, 51, 3471– 3479 DOI: 10.1021/acs.est.7b00339 ; Efficient and Selective Uptake of TcO4– by a Cationic Metal–Organic Framework Material with Open Ag+ Sites 
3) Zhu, L.; Sheng, D.; Xu, C.; Dai, X.; Silver, M. A.; Li, J.; Li, P.; Wang, Y.; Wang, Y.; Chen, L.; Xiao, C.; Chen, J.; Zhou, R.; Zhang, C.; Farha, O. K.; Chai, Z.; Albrecht-Schmitt, T. E.; Wang, S. J. Am. Chem. Soc. 2017, 139, 14873– 14876, DOI: 10.1021/jacs.7b08632 ; Identifying the Recognition Site for Selective Trapping of 99TcO4– in a Hydrolytically Stable and Radiation Resistant Cationic Metal–Organic Framework 
4) Fang, H.; Chen, J.; Balogun, M.; Tong, Y.; Zhang, J.; ACS App. Nano Mater. 2018, 1(11), 6477-6482, DOI:10.1021/acsanm.8b01697 ; Covalently Modified Electrode with Pt Nanoparticles Encapsulated in Porous Organic Polymer for Efficient Electrocatalysis
5) Li, D.; Ren, Z.; Young, D.; Lang, J.; Euro. J. Inorg. Chem. 2015), 2015(11), 1981-1988, DOI:10.1002/ejic.201500069 ; Synthesis of Two Coordination Polymer Photocatalysts and Significant Enhancement of Their Catalytic Photodegradation Activity by Doping with Co2+ Ions

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