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3,3',6,6'-四羧酸-4,4'-联吡啶

[4,4'-Bipyridine]-2,2',6,6'-tetracarboxylic acid

CAS NO.:124558-60-7分子式:C14H8N2O8分子量:332.22192
产品名称:[4,​4'-​Bipyridine]​-​2,​2',​6,​6'-​tetracarboxylic acid
其他名称:H4BPTCA; 3,3',6,6'-四羧酸-4,4'-联吡啶
CAS:124558-60-7
结构信息
分子式  C14H8N2O8 分子量  332.22192
性状照片
性质说明
1) 微溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为中间体用于合成MOF材料: 如[Mn2(BPTCA)​(phen)​2·H2O]​n [r3]
表征图谱
HNMR
 
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Huenig, S.; Wehner, I. Synthesis 1989, 7, 552-554
2) Lin, X., Blake, A. J., Wilson, C., Sun, X. Z., Champness, N. R., George, M. W., Hubberstey, P., Mokaya, R., and Schröder, M. J. Am. Chem. Soc. 2006, 128, 10745-10753, DOI: 10.1021/ja060946u ; A Porous Framework Polymer Based on a Zinc(II) 4,4‘-Bipyridine-2,6,2‘,6‘-tetracarboxylate:  Synthesis, Structure, and “Zeolite-Like” Behaviors 
3) Bai, Z. S.; Qi, Z. P.; Lu, Y.; Yuan, Q.; Sun, W. Y. Crystal Growth Des. 2008, 8, 1924-1931 DOI: 10.1021/cg7011952 ; Novel Inorganic–Organic Hybrid Frameworks of Manganese(II): Syntheses, Crystal Structures, and Physical Properties 
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