产品名称：1,1'-butadiynebenzene-3,3',5,5'-tetracarboxylic acid
其他名称：H4BDDC ; H4BBTC ; DPBDTC;5,5'-(1,3-Butadiyne-1,4-diyl)bis[1,3-benzenedicarboxylic acid] ; 5,5'-(butadiyne-1,4-diyl)diisophthalic acid ; 1,4-diphenyl-1,3-butadiyne-3,3′′,5,5′′-tetracarboxylic acid
CAS：1239608-21-9
3) Stannard, Andrew; Russell, James C.; Blunt, Matthew O.; Salesiotis, Christos; Gimenez-Lopez, Maria del Carmen; Taleb, Nassiba; Schroeder, Martin; Champness, Neil R.; Garrahan, Juan P.; Beton, Peter H.; Nature Chem. 2012, 4(2), 112-117, DOI: 10.1038/nchem.1199 ; Broken symmetry and the variation of critical properties in the phase behaviour of supramolecular rhombus tilings
4) Rong, Jiewei; Zhang, Wenwei; Bai, Junfeng; RSC Adv. 2016, 6(105), 103714-103723, DOI: 10.1039/C6RA22001K ; Synthesis and structure of color tunable and white-light emitting lanthanide metal-organic framework materials constructed from conjugated 1,1'-butadiynebenzene-3,3',5,5'-tetracarboxylate ligand
其他名称：H4BDDC ; H4BBTC ; DPBDTC;5,5'-(1,3-Butadiyne-1,4-diyl)bis[1,3-benzenedicarboxylic acid] ; 5,5'-(butadiyne-1,4-diyl)diisophthalic acid ; 1,4-diphenyl-1,3-butadiyne-3,3′′,5,5′′-tetracarboxylic acid
CAS：1239608-21-9
结构信息
| 分子式 | C20H10O8 | 分子量 | 378.2886 | ||
| 性状照片 | |||||
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:[Cu2(BDDC)(H2O)2]·DMF·3H2O [r1]; [Eu2(BBTC)1.5(CH3OH)2(H2O)2] [r2]; [Ln2(BBTC)1.5(DMF)4] [r4]
表征图谱
参考文献
1) Zheng, Bing; Liang, Zhiqiang; Li, Guanghua; Huo, Qisheng; Liu, Yunling; Cryst. Growth & Des. 2010, 10(8), 3405-3409, DOI: 10.1021/cg100046j ; Synthesis, Structure, and Gas Sorption Studies of a Three-Dimensional Metal-Organic Framework with NbO Topology
2) Wang, Li-Feng; Kang, Ling-Chen; Zhang, Wen-Wei; Wang, Fang-Ming; Ren, Xiao-Ming; Meng, Qing-Jin; Dalton Trans. 2011, 40(37), 9490-9497, DOI: 10.1039/c1dt10693g ; New europium coordination polymers with efficient energy transfer from conjugated tetracarboxylate ligands to Eu3+ ion: syntheses, structures, luminescence and magnetic properties5) Shao, Kai; Pei, Jiyan; Wang, Jia-Xin; Yang, Yu; Cui, Yuanjing; Zhou, Wei; Yildirim, Taner; Li, Bin; Chen, Banglin; Qian, Guodong; Chem. Commun. 2019, 55(76), 11402-11405, DOI: 10.1039/c9cc06239d ; Tailoring the pore geometry and chemistry in microporous metal-organic frameworks for high methane storage working capacity
