产品名称：1,3,5-Benzene-tri-p-phenylphosphonic acid
其他名称：H6PPB;P,P'-[5'-(4-Phosphonophenyl)[1,1':3',1''-terphenyl]-4,4''-diyl]bis[phosphonic acid]
CAS：1045720-71-5
3) Mah, Roger K.; Lui, Melanie W.; Shimizu, George K. H.; Inorg. Chem. 2013, 52(13), 7311-7313, DOI: 10.1021/ic400274e ; Enhancing Order and Porosity in a Highly Robust Tin(IV) Triphosphonate Framework
4) Pili, Simona; Argent, Stephen P.; Morris, Christopher G.; Rought, Peter; Garcia-Sakai, Victoria; Silverwood, Ian P.; Easun, Timothy L.; Li, Ming; Warren, Mark R.; Murray, Claire A.; Tang, Chiu C.; Yang, Sihai; Schroder, Martin; J. Am. Chem. Soc. 2016, 138(20), 6352-6355, DOI: 10.1021/jacs.6b02194 ; Proton Conduction in a Phosphonate-Based Metal-Organic Framework Mediated by Intrinsic "Free Diffusion inside a Sphere"
其他名称：H6PPB;P,P'-[5'-(4-Phosphonophenyl)[1,1':3',1''-terphenyl]-4,4''-diyl]bis[phosphonic acid]
CAS：1045720-71-5
结构信息
| 分子式 | C24H21O9P3 | 分子量 | 546.33954 | ||
| 性状照片 | |||||
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:CALF-28 [r3]; MFM-500(M) (M = Ni, Co) [r4]; CAU-25 / [Zn2(H2PPB)(H2O)2] [r5]
表征图谱
参考文献
1) Beckmann, Jens; Ruettinger, Roman; Schwich, Torsten; Cryst. Growth & Des. 2008, 8(9), 3271-3276, DOI: 10.1021/cg8000569 ; 1,3,5-Benzene-tri-p-phenylphosphonic acid. A new building block in supramolecular chemistry
2) Ouellette, Wayne; Wang, Guangbin; Liu, Hongxue; Yee, Gordon T.; O'Connor, Charles J.; Zubieta, Jon; Inorg. Chem. 2009, 48(3), 953-963, DOI: 10.1021/ic801450m ; The Hydrothermal and Structural Chemistry of Oxovanadium-Arylphosphonate Networks and Frameworks5) Hermer, N.; Reinsch, H.; Mayer, P.; Stock, N.; CrystEngComm 2016, 18(42), 8147-8150, DOI: 10.1039/C6CE01580H ; Synthesis and characterisation of the porous zinc phosphonate [Zn2(H2PPB)(H2O)2]·xH2O
