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5-[(3,5-二羧基苯基)甲基]苯-1,3-二羧酸

5-[(3,5-dicarboxyphenyl)methyl]benzene-1,3-dicarboxylic acid

CAS NO.:10397-52-1分子式:C17H12O8分子量:344.27238
产品名称:5,​5'-​Methylenediisophthal​ic acid
其他名称:H4mdip; H4MDIA;Isophthalic acid, 5,​5'-​methylenedi- )​; 5,​5'-​Methylenebis[1,​3-​benzenedicarboxylic acid]​;
CAS:10397-52-1
结构信息
分子式 C17H12O8 分子量 344.27238
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:[Zn(H2MDIP)​(4,​4'-​bpy)​0.5] [r1]; [NH2Me2]​[Ln(MDIP)​(H2O)​] [r3]; MIP-177 [r4]
表征图谱
HNMR
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Duan, Xianying; Li, Yizhi; Su, Yang; Zang, Shuangquan; Zhu, Chengjian; Meng, Qingjin; CrystEngComm 2007, 9(9), 758-766, DOI: 10.1039/b618613k ; Syntheses and solid state structures of hybrid d10 metal-​organic frameworks based on methylenediisophthalic acid (H4MDIP)
2) Wang, Xi-Sen; Ma, Shengqian; Forster, Paul M.; Yuan, Daqiang; Eckert, Juergen; Lopez, Joseph J.; Murphy, Brandon J.; Parise, John B.; Zhou, Hong-Cai; Angew. Chem. Int., Ed. 2008, 47(38), 7263-7266, DOI: 10.1002/anie.200802087 ; Enhancing H2 uptake by "close-​packing" alignment of open copper sites in metal-​organic frameworks
3) Su, Shengqun; Chen, Wan; Qin, Chao; Song, Shuyan; Guo, Zhiyong; Li, Guanghua; Song, Xuezhi; Zhu, Min; Wang, Song; Hao, Zhaomin; Zhang, Hongjie; Cryst. Growth & Des. 2012, 12(4), 1808-1815, DOI: 10.1021/cg201283a ; Lanthanide Anionic Metal-​Organic Frameworks Containing Semirigid Tetracarboxylate Ligands: Structure, Photoluminescence, and Magnetism
4) Wang, Sujing; Kitao, Takashi; Guillou, Nathalie; Wahiduzzaman, Mohammad; Martineau-Corcos, Charlotte; Nouar, Farid; Tissot, Antoine; Binet, Laurent; Ramsahye, Naseem; Devautour-Vinot, Sabine; Kitagawa, Susumu; Seki, Shu; Tsutsui, Yusuke; Briois, Valerie; Steunou, Nathalie; Maurin, Guillaume; Uemura, Takashi; Serre, Christian; Nature Commun. 2018, 9(1), 1-9, DOI: 10.1038/s41467-018-04034-w ; A phase transformable ultrastable titanium-carboxylate framework for photoconduction
10397-52-1-CS014885.pdf 下载

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